Methods for polynucleotide synthesis and articles for polynucleo

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing compound containing saccharide radical

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435 6, 435 912, 435 9121, 536 231, 536 243, 536 2431, 536 2432, 536 2433, C12P 1934, C12Q 168, C07H 2102

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060837268

ABSTRACT:
This invention relates to methods for making polynucleotides of any desired nucleotide sequence by repeating a series of reactions involving assembly of overlapping oligomers, ligation by DNA ligase, and cleavage with a restriction enzyme that cuts so as to add one or more additional nucleotides to a growing polynucleotide. This invention also relates to combining such a method for polynucleotide synthesis with a step employing localized melting of hybridized DNA oligomers, to synthesize an array of polynucleotides of different, defined nucleotide sequence on a substrate, and to the articles for polynucleotide hybridization so made. This invention further includes methods in which a substrate bearing an array of polynucleotides made according to the invention is used to determine the nucleotide sequence of a nucleic acid, or to detect or isolate a nucleic acid having a selected nucleotide sequence, and a device which analyzes a substrate-bound array of polynucleotides made according to the invention to determine the nucleotide sequence of a nucleic acid, or to detect or isolate a nucleic acid having a selected nucleotide sequence.

REFERENCES:
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Brown, David, "DNA-Encoded Chips Appear to Speed Tests for Genetic Mutations," The Washington Post, Nov. 24, 1997.
Mirkin, Chad A., et al., Nature 382:607-609 (1996).
Pease, Ann Caviani, et al, Proc. Natl. Acad. Sci. 91:5022-5026 (1994).
McGall, Glenn H., et al., J. of the Amer. Chem. Soc. 119(22):5082-5090 (1997).
Luo et al, "Improving the fidelity of Thermus thermophilus DNA ligase", Nucleic Acids Research 24(14):3071-3078, 1996.
Deng et al, "Basis for selection of improved carbohydrate binding single chain antibodies from synthetic gene libraries", Proc. Natl. Acad. Sci. 92:4992-4996, May 1995.

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