Methods for optimal usage and improved valuation of...

Chemistry: analytical and immunological testing – Geochemical – geological – or geothermal exploration – For petroleum oils or carbonaceous minerals

Reexamination Certificate

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C436S055000, C436S164000

Reexamination Certificate

active

10663566

ABSTRACT:
The invention is a method to improve the prediction of the corrosivity of organic acids in petroleum crudes, feedstocks and distillation fractions by providing a more accurate, repeatable, and rapid means of determining the TAN from the IR spectrum of the material. The method can be easily practiced in refinery, terminal, and assay laboratories. It can be used in conjunction with models and hardware to optimize the usage and improve the valuation of corrosive feed stocks. The invention can be implemented on-line for blending optimization. It comprises the steps of irradiating a heated petroleum sample with IR radiation to produce its IR absorption spectrum, and predicting the TAN from the spectrum using a linear, multivariate regression model. The IR TAN value is then used as input to blending, valuation, and corrosion models.

REFERENCES:
patent: 5420041 (1995-05-01), Matsushita et al.
patent: 5681749 (1997-10-01), Ramamoorthy
Dong et all. “Rapid determination of the carboxylic acid contribution to the total acid namber of lubricants by FTIR” http://www.thermal-lube.com/english/research/publications/mcgill—TANfinal.pdf, crated on-line Jul. 7, 2005.
Robinson et al. “Monitoring oil degradation with infrared spectroscopy”, http://www.wearcheck.ca/literature/techdoc/WZA018.pdf, created on-line Sep. 16, 2000.
“Automated FTIR Method for Determination of the Base Number of Lubricants as an Alternative to ASTM D2896 . . . ” http://www.priorartdatabase.com/IPCOM/000126654/.
Van de Voort “FTIR Acid and Base Number Analyses: Their Potential to Replace ASTM Methods” http://www.thermal-lube.com/english/analytical/publications/TANTBNreplace.htm, 2001.

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