Methods for generating light with chemiluminescent dioxetanes ac

Chemistry: analytical and immunological testing – Optical result – With fluorescence or luminescence

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435 772, 435 19, 435 21, 549332, 549510, G01N 2176, G01N 3353, C12Q 144, C07D30300

Patent

active

052486184

ABSTRACT:
Novel assay methods employing compounds which are chemically or enzymatically cleavable and which give rise to an intermediate which further decomposes by an intramolecular anchimeric displacement reaction which releases a signal producing species are disclosed. Also disclosed are probe hybridization assays employing the compounds of the invention employing thermostable enzymes which are not denatured by the hybridization conditions. Such signal producing species may include chemiluminescent dioxetanes and other colored products.

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Washburn and Dennis, "Novel General Approach for the Assay and Inhibition of Hydrolytic Enzymes Utilizing Suicide-Inhibitory Bifunctionally Linked Substrates (SIBLINKS): Exemplified by a Phosphilipase A.sub.2 Assay," J. Am. Chem. Soc. 112(5):2040-2041 (1990).
Washburn and Dennis, "Suicide-Inhibitory Bifunctionally Linked Substrates (SIBLINKS) as Phospholipase A.sub.2 Inhibitors," J. Am. Chem. Soc. 112(5):2042-2043 (1990).
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