Methods and compounds for making coatings, waveguides and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

Reexamination Certificate

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C556S454000

Reexamination Certificate

active

06924384

ABSTRACT:
A compound of the general formula R1R2MR4R5is disclosed wherein R1and R2are independently an aryl, alkyl, alkenyl, epoxy or alkynyl group, wherein at least one of R1and R2is fully or partially fluorinated, wherein M is selected from group 14 of the periodic table, wherein R4and R5are independently an alkoxy group, OR3, or a halogen group, X, except where M is Si, R4and R5are both ethoxy groups or both chlorine groups, and R1and R2are perfluorinated groups. This compound formed can be further reacted to attach an additional organic R group, and/or hydrolyzed, alone or with one or more similar compounds, to form a material having a molecular weight of from 500 to 10,000, which material can be deposited on various substrates as a coating or deposited and patterned for a waveguide or other optical device components. Methods for making compounds of the general formula R1MR4R5R6are also disclosed.

REFERENCES:
patent: 3853726 (1974-12-01), Vainshiein et al.
patent: 5973176 (1999-10-01), Roscher et al.
Frohn et al., Preparation of halogeno(pentafluorophenyl)silanes from pentafluorophenyl(phenyl)silanes, Journal of Organometallic Chemistry, 1998, 568 (1-2), 233-240.□□.
Whittingham et al., A Direct Preparation of Some Pentafluorophenyl-Containing Silanes Journal of Organometallic Chemistry, 13 (1968) 125-129.
Lappert et al., Perfluoropheny-Silicon Compounds, Chemical Communications (London), 1968, 13, 750-751.
Bardin et al., Fluorination of C6F5MX3 Compounds, Journal of Fluorine Chemistry, 60 (2-3), 141-151.

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