Chemistry: fischer-tropsch processes; or purification or recover – Including regeneration of catalyst – Solvent utilized
Patent
1997-02-06
2000-09-05
Padmanabhan, Sreeni
Chemistry: fischer-tropsch processes; or purification or recover
Including regeneration of catalyst
Solvent utilized
518700, 518724, 252373, 502 22, 502 29, 502326, C07C 2700, C07C 102, B01J 2034
Patent
active
061143995
ABSTRACT:
A method of separating a Fischer-Tropsch catalyst from the output slurry of a Fischer-Tropsch bubble column reactor, where the slurry comprises Fischer-Tropsch catalyst particles and liquid hydrocarbon product is disclosed. The method comprises contacting a compressed hydrocarbon solvent (e.g., a supercritical hydrocarbon solvent, or liquid hydrocarbon solvent which may be at near supercritical conditions) with the output slurry at a temperature and pressure where the liquid hydrocarbon product is soluble in the solvent to form a concentrated slurry phase containing the catalyst particles, and an enriched solvent phase containing liquid hydrocarbon product. This contacting step is then followed by the step of separating the concentrated slurry from the enriched solvent. Apparatus for carrying out the method of the invention is also disclosed.
REFERENCES:
patent: 4162965 (1979-07-01), Clapper
patent: 4605678 (1986-08-01), Brennan et al.
R. R. Schehl; Rose.RTM. Process Solves the LaPorte Catalyst/Wax Separation Problem Jun. 28, (1992).
P.Z. Zhou, Status Review of Fischer-Tropsch Slurry Reactor Catalyst/Wax Separation Techniques, Burns & Roe Services Corp. (1991).
W.O. Eisenbach et al., Supercritical Fluid Extration of Oil Sands and Residues From Oil and Coal Hydrogenation, Chemical Engineering at Supercritical Fluid Conditions, 20 pp 419-433 (1983).
D. Stutzer et al., Separation of Finely Dispersed Solids From Low-Volatile Viscous Media By Gas Extraction, Chemical Engineering at Supercritical Fluid Conditions 21, pp 435-443 (1983).
H. Kolbel, et al., The Fischer-Tropsch Synthesis in the Liquid Phase, Catal. REv. -Sci. Enc., 21, 225-274 (1980).
K. Mc Gee, A Better Bottom Line From The Bottom Of The Barrel, Rose Supercritical Fluid Technology, (1992).
Kilpatrick Peter K.
Roberts George W.
North Carolina State University
Padmanabhan Sreeni
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