Methods and apparatus for recovering gypsum and magnesium...

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

Reexamination Certificate

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C423S243110, C423S244070, C423S555000, C423S635000, C423S636000, C423S155000, C423S158000, C423S164000, C423S166000, C423S169000, C423S170000

Reexamination Certificate

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11324620

ABSTRACT:
The present invention provides methods and apparatus for treating flue gas containing sulfur dioxide using a scrubber, and more particularly relates to recovering gypsum and magnesium hydroxide products from the scrubber blowdown. The gypsum and magnesium hydroxide products are created using two separate precipitation reactions. Gypsum is crystallized when magnesium sulfate reacts with calcium chloride. Magnesium hydroxide is precipitated when magnesium chloride from the gypsum crystallization process reacts with calcium hydroxide. The process produces a high quality gypsum with a controllable pH and particle size distribution, as well as high quality magnesium hydroxide.

REFERENCES:
patent: 4867961 (1989-09-01), Palmer
patent: 5084255 (1992-01-01), College et al.
patent: 5270026 (1993-12-01), College et al.
patent: 5614158 (1997-03-01), College
patent: 5676915 (1997-10-01), Iiyama et al.
patent: 6214313 (2001-04-01), Berisko et al.

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