Method to retard catalyst recrystallization

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Inorganic carbon containing

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427115, 429 40, 429 44, 502101, B01J 2364, B01J 2342, H01M 488, H01M 486

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active

049372203

ABSTRACT:
The rate of noble metal crystallite recrystallization on a carbon-supported noble metal catalyst is reduced by dispersing two or more different kinds of noble metal-containing crystallites onto the surface of the carbon support. The crystallites have either different unit cell configurations or different unit cell sizes. The reduced rate of noble metal crystallite recrystallization results, over a period of time, in higher crystallite surface area and therefore, better catalyst performance compared to conventional carbon-supported noble metal catalysts. Fuel cells which incorporate such improved catalysts as cathode catalysts are capable of operating at maximum power production for longer periods of time than fuel cells which use conventional catalysts as cathode catalysts.

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