Method to reduce fuel vapor emissions

Gas separation: processes – Solid sorption – Organic gas or liquid particle sorbed

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95146, 95900, B01D 5304

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active

052883078

ABSTRACT:
Hydrocarbon emissions from fuel reservoirs, particularly those associated with motor vehicles, are abated by contacting a vented hydrocarbon fuel vapor stream from the reservoirs with a polymeric adsorbent derived from a macroporous or macroreticular copolymer of at least one monovinylidene aromatic monomer and a crosslinking monomer. The macroporous copolymers are converted into suitable adsorbents by post-polymerization crosslinking in a swollen state in the presence of a Friedel-Crafts catalyst. The resulting adsorbent has improved hydrocarbon adsorption capacity relative to conventional activated carbon adsorbents.

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