Method to reduce crystal defects particularly in group...

Single-crystal – oriented-crystal – and epitaxy growth processes; – Processes of growth with a subsequent step of heat treating...

Reexamination Certificate

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C117S002000, C117S004000, C117S007000, C117S084000, C117S088000, C117S092000, C117S094000, C117S098000, C117S103000, C117S107000, C117S108000, C117S904000, C117S905000, C117S952000

Reexamination Certificate

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07341628

ABSTRACT:
Gallium Nitride layers grown as single crystals by epitaxy such as Hydride Vapor Phase Epitaxy (HVPE) contain large numbers of crystal defects such as hexagonal pits, which limit the yield and performance of opto- and electronic devices. In this method, the Gallium Nitride layer is first coated with an Aluminum layer of approximate thickness of 0.1 microns. Next, Nitrogen is ion implanted through the Aluminum layer so as to occupy mostly the top 0.1 to 0.5 microns of the Gallium Nitride layer. Finally, through a pulsed directed energy beam such as electron or photons, with a fluence of approximately 1 Joule/cm2the top approximately 0.5 microns are converted to a single crystal with reduced defect density.

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patent: 6358766 (2002-03-01), Kasahara
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Patent Abstracts of Japan. English Abstract of JP 61-251599 (1986).
Geppert, L., “The Great Gallium Nitride Gamble”, IEEE Spectrum, Jan. 2004, pp. 52-59.
Tan, H.,H., et.al., “ Annealing of ion implanted gallium nitride”, Applied Physics Letters, V. 72, No. 10, pp. 1190-1192, 1998.

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