Method to reduce carboxybenzaldehyde isomers in terephthalic aci

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C 51487

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059292741

ABSTRACT:
A method for reducing carboxybenzaldehyde isomers in crude terephthalic and/or isophthalic acids is described. Crude TPA or IPA is dissolved in N-methyl pyrrolidone and is subsequently contacted with an oxidant, such as substantially anhydrous hydrogen peroxide, to convert the carboxybenzaldehyde isomer (4-CBA or 3-CBA) to TPA or IPA under moderate temperature and pressure conditions.

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