Method to produce and purify cyclic esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

549349, C07D32100, C07D32110

Patent

active

056750218

ABSTRACT:
Methods are provided for the production, recovery and purification of cyclic esters. Such methods include producing a cyclic ester composition containing at least one impurity, contacting the cyclic ester composition with at least one adsorbent to remove the impurity and recovering the purified cyclic esters. Also included are methods of cyclic ester purification involving multiple adsorption operations. The methods of the present invention can produce highly purified cyclic esters. Such compositions are suitable for use in the manufacture of polymers having an average degree of polymerization in excess of about 1700.

REFERENCES:
patent: 1095205 (1914-05-01), Gruter et al.
patent: 1594843 (1926-08-01), Lawrie
patent: 1906068 (1933-04-01), Jenemann
patent: 1995970 (1935-03-01), Dorough
patent: 2163268 (1939-06-01), Carothers et al.
patent: 2174491 (1939-09-01), Watson
patent: 2189572 (1940-02-01), Watson
patent: 2668162 (1954-02-01), Lowe
patent: 2703316 (1955-03-01), Schneider
patent: 2758987 (1956-08-01), Salzberg
patent: 2768973 (1956-10-01), Castle et al.
patent: 3322719 (1967-05-01), Peilstocker
patent: 3371112 (1968-02-01), Winstrom et al.
patent: 3435008 (1969-03-01), Schmitt et al.
patent: 3457280 (1969-07-01), Schmitt et al.
patent: 3597450 (1971-08-01), Schmitt et al.
patent: 3736646 (1973-06-01), Schmitt et al.
patent: 3867190 (1975-02-01), Schmitt et al.
patent: 3960152 (1976-06-01), Augurt et al.
patent: 4033938 (1977-07-01), Augurt et al.
patent: 4045418 (1977-08-01), Sinclair
patent: 4070375 (1978-01-01), Suzuki
patent: 4435595 (1984-03-01), Agreda et al.
patent: 4650851 (1987-03-01), Rhum et al.
patent: 4727163 (1988-02-01), Bellis
patent: 4730082 (1988-03-01), Amiet
patent: 4771001 (1988-09-01), Bailey et al.
patent: 4797468 (1989-01-01), De Vries
patent: 4835293 (1989-05-01), Bhatia
patent: 4939294 (1990-07-01), Agreda et al.
patent: 4966982 (1990-10-01), Ono et al.
patent: 4990222 (1991-02-01), Aigner et al.
patent: 5023349 (1991-06-01), Bhatia
patent: 5023350 (1991-06-01), Bhatia
patent: 5043458 (1991-08-01), Bhatia
patent: 5053485 (1991-10-01), Nieuwenhuis et al.
patent: 5053522 (1991-10-01), Muller
patent: 5068418 (1991-11-01), Kulprathipanja et al.
patent: 5075115 (1991-12-01), Brine
patent: 5089632 (1992-02-01), Paul
patent: 5091544 (1992-02-01), Bhatia
patent: 5236560 (1993-08-01), Drysdale et al.
patent: 5264592 (1993-11-01), Fridman et al.
patent: 5310599 (1994-05-01), Ford
Alen et al., "Condensation of Glycolic, Lactic and 2-Hydroxybutanoic Acids During Heating and Identification of the Condensation Products by GLC-MS", pp. 633-636, 1980, Acta Chemica Scandinavica B, vol. 34, No. 9.
Bezzi et al., "Dehydration Products of Lactic Acid Typifying the Transformation of Cyclic Esters into Linear Polyesters", 1936, Meeting of the Italian Academy of Science, Nov.
Bezzi, "The Constitution of Some Polyglycxolides", pp. 219-233, 1949, Gazz Chim. Ital. vol. 79.
Busche, "Recovering Chemical Products From Dilute Fermentation Broths", pp. 597-615, 1983, Biotechnology and Bioengineeering Symp., No. 13.
Carothers, "Polymers and Polyfunctionality", pp. 39-53, 1936, Transactions of the Faraday Society, vol. 32.
Carothers et al., "Studies of Polymerization and Ring Formation, X. The Reversible Polymerization of Six-Membered Cyclic Esters", p. 761-771, 1932, J. Am. Chem. Soc., vol. 54.
Cleary et al., "Separation of Closely Boiling Mixtures By Reactive Distillation 2. Experiments", pp. 1071-1073, 1985, Ind. Eng. Chem. Process Des. Dev., vol. 24.
Dadgar et al., "Improving The Acetone-Butanol Fermentation Process With Liquid-Liquid Extraction", pp. 36-39, 1988, Biotechnology Progress, vol. 4, No. 1.
Dahlmann, Jurgen; et al.; "Synthesis and Properties of Biodegradable Aliphatic Polyesters", British Polymer Journal 23 (1990), pp. 235-240.
DeGarmo et al., "Consider Reactive Distillation", pp. 43-50, 1992, Chemical Engineering Progress, Mar.
Deibig et al., "I. Synthesis and Properties of Polytetramethyl Glycolide", pp. 123-131, 1971, Die Makromolekulare Chemie, vol. 145.
Deibig et al., "II. Thermal Behavior of Polytetramethyl Glycolide", pp. 133-139, 1971, Die Makromolekulare Chemie, vol. 145.
Earhart et al., "Waste Recovery: Recovery of Organic Pollutants Via Solvent Extraction," pp. 67-73, 1977, Cep, May.
Filachione et al., "Lactic Acid Condensation Polymers: Preparation By Batch And Continuous Methods", p. 223-228, 1944, Industrial And Engineering Chemistry, Mar. vol. 36, No. 3.
Hill et al., "Cyclic And Polymeric Formals", pp. 925-928, 1935, J. Am. Chem. Soc., vol. 57.
Holten, "Lactic Acid. Properties And Chemistry Of Lactic Acid And Derivatives", pp. 221-231, 1971, Verlag Chemie.
Ikada et al., "Stereocomplex Formation Between Enantiomeric Poly(Lactides)", pp. 904-906, 1987, American Chemical Society, Macromolecules, 20.
Imasaka et al., "Synthesis Of Degradable Terpolymers Responding To External Stimuli Such As PH, Ionic Strength, And Temperature", pp. 715-722, 1991, Makromol. Chem. vol. 192.
Jackanicz et al., "Polylactic Acid As A Biodegradable Carrier For Contraceptive Steroids", pp. 227-234, 1973, The Population Counsel, Sep., vol. 8, No. 3.
Jungfleisch et al., "Organic Chemistry--Of Lactyllactyllactic Acid And The Dilactide Of Racemic Lactic Acid", pp. 502-505, 1905, Academie Des Sciences, Meeting Of 20 Feb.
Jungfleisch et al., "Organic Chemistry--On The Dilactide Of Left Lactic Acid", pp. 637-639, 1906, Academic Des Sciences, Meeting of 12 Mar.
Jungfleisch et al., "Organic Chemistry--On The Dilactide Of The Right", pp. 111-113, 1905 Academie Des Sciences, Meeting Of 10 Jul.
Jungfleisch et al., "Organic Chemistry--On Inactive Dilactylic Acid", p. 979, 1907, Academie Des Sciences, Meeting of 6 May.
Jungfleisch et al., "Organic Chemistry--On Ethyl Lactyllactate", 1907, Academie Des Sciences, Meeting of 25 Feb.
Kawabata, Nariyoshi et al.; "Removal and Recovery of Organic Pollutants From Aquatic Environment. 4. Separation of Carboxylic Acids From Aqueous Solution Using Cross-Linked Poly(4-Vinylpyridine)," Ind. Eng. Chem. Prod. Res. Dev., vol. 20, pp. 386-390, 1981.
King, "Amine-Based Systems For Carboxylic Acid Recovery", pp. 285-291, 1992, Chemtech, Mar.
Kleine et al., "High Molecular Weight, Especially Optically Active Polyesters of Lactic Acid: An Investigation of the Stereochemistry Of Macromolecular Compounds", pp. 1-21, (1958), Report from the Research Laboratory for Macromolecular Chemistry, Dec.
Kulkarni et al., "Polylactic Acid for Surgical Implants", pp. 839-843, 1966, Arch. Surg., vol. 93, Nov.
Light, "Lactic Acid Resins", pp. 135-136, 1940, Paint Manufacture, Jun.
Marlatt et al., "Acetone-Butanol Fermentation Process Development and Economic Evaluation", pp. 23-28, 1986, Biotechnology Progress, vol. 2, No. 1.
Montgomery, "Acidic Constituents Of Lactic Acid-Water Systems", pp. 1466-1468, 1952, J. Am. Chem. Soc., vol. 74.
Othmer, "Acetic Acid Recovery Methods", pp. 48-59, 1958, Chemical Engineering Progress, vol. 54, No. 7.
Reillex Report 6, "Pollution Control", Published By Reilly Industries, Inc., Copyright 1989.
Ricker et al., "Solvent Extraction For Treatment Of Wastewaters From Acetic-Acid Manufacture," pp. 204-209, 1978, The American Institute Of Chemical Engineers, vol. 74, No. 178.
Tamada et al., "Extraction of Carboxylic Acids With Amine Extractants. 1. Equilibria And Law Of Mass Action Modeling", p. 1319-1326, 1990, Ind. Eng. Chem. Res., vol. 29, No. 7.
Tamada et al., "Extraction Of Carboxylic Acids With Amine Extractants. 2. Chemical Interactions And Interpretation Of Data," pp. 1327-1333, 1990, Ind. Eng. Chem. Res., vol. 29, No. 7.
Tamada et al., "Extraction of Carboxylic Acids with Amine Extractants. 3. Effect of Temperature, Water Coextraction, and Process Considerations," pp. 1333-1338, 1990, Ind. Eng. Chem., Res., vol. 29, No. 7.
Terrill et al., "Separation of Closely Boiling Mixtures by Reactive Distillation 1. Theory," p. 1062-1071, 1985,Ind. Eng. Chem. Process Des. Dev., vol. 24, No. 4.
Watson, "Composition of Lactic Acid. Production of a Highly Concentrated Acid", pp. 399-401, 1940, Industrial and Engineering Chemistry, vol. 32, No. 3.
Wise, "B

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Method to produce and purify cyclic esters does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method to produce and purify cyclic esters, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method to produce and purify cyclic esters will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2358534

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.