Method to increase the flow capacity of a geologic formation

Wells – Processes – Distinct – separate injection and producing wells

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166300, 166307, E21B 4327

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active

053756606

ABSTRACT:
Minerals in a subterranean formation are dissolved by treating them in the presence of an organic acid with a fluoride-containing compound having a concentration in the range of from 0.007 N to 0.05 N. The hydrogen ion concentration can be less than 0.02 N, preferably less than 0.004 N. The fluoride-containing compound can be hydrofluoric acid. Alternatively, the minerals can be treated by applying alternating stages of a solution of fluoride salt, such as ammonium fluoride or ammonium bifluoride, and an organic acid, such as acetic acid. The treatment can be done in a formation at a temperature of at least 350.degree. F.

REFERENCES:
patent: 2094479 (1937-09-01), Vandergrift et al.
patent: 3953340 (1976-04-01), Templeton et al.
patent: 4056146 (1977-11-01), Hall
patent: 4090563 (1978-05-01), Lybarger et al.
patent: 4414118 (1983-11-01), Murphey
patent: 5082058 (1992-01-01), Blumer
H. Perthuis et al., Acid Reactions and Damage Removal in Sandstones: A Model for Selecting the the Acid Formulation, 11, 125-136 (1969).
Society of Petroleum Engineers, Formation Damage Control, 2, 552-553 (1992).

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