Method to improve acidulation quality of North Carolina phosphat

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkaline earth metal

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C01B 2516

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active

045579091

ABSTRACT:
Phosphate rock is heated under controlled conditions to essentially eliminate organic impurities and sulfides from the rock and subsequently leached with water to substantially increase the porosity and surface area of the calcined solid and remove any traces of sulfide still remaining in the calcine. This process yields an improved calcined product rendered more suitable for acidulation to wet-process phosphoric acid and is beneficial for apatitic phosphate rocks possessing a moderate to high content of organic impurities and a high degree of carbonate substitution in the apatite crystal lattice.

REFERENCES:
patent: 3995987 (1976-12-01), MacAskill
patent: 4017585 (1977-04-01), Angevine et al.
patent: 4321238 (1982-03-01), Henin
patent: 4325928 (1982-04-01), Lowe
patent: 4389380 (1983-06-01), Parks

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