Method of upgrading oils containing hydroxyaromatic hydrocarbon

Chemistry of hydrocarbon compounds – Production of hydrocarbon mixture from refuse or vegetation

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208 49, 208 58, 208 67, 208 68, 585242, 585469, C07C 100

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active

051808684

ABSTRACT:
The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

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"Chemistry of Catalytic Hydrodeoxygenation," E. Furmisky, Energy Research Laboratories, Catal. Rev.-Sci. Eng., 25(3) 421-458 (1983).
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Haider, Ghulam "Catalytic Hydrodeoxygenation of Coal-Derived Liquids and Related Oxygen-Containing Compounds," a dissertation submitted to the faculty of The University of Utah in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Fuels Engineering, Department of Mining and Fuels Engineering, The University of Utah, Dec. 1981.
Skukla, Yagya Valkya "Catalytic Hydrodeoxygenation Studies of Aromatic Ethers, Phenols and Oxygen-Rich Synfuels," a dissertation submitted to the faculty of The University of Utah in partial fulfillment of the requirements for the degree of Doctor of Philosophy, Department of Mining and Fuels Engineering, The University of Utah, Aug. 1985.

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