Method of trivalent chromium concentration determination by...

Chemistry: analytical and immunological testing – Metal or metal containing – Ti – zr – hf – va – nb – ta – cr – mo – w

Reexamination Certificate

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C436S074000, C436S053000

Reexamination Certificate

active

07148068

ABSTRACT:
A method is disclosed for determining the concentration of trivalent chromium Cr(III) in a sample. The addition of perchloric acid has been found to increase the atomic chromium spectrometric signal due to Cr(III), while leaving the signal due to hexavalent chromium Cr(VI) unchanged. This enables determination of the Cr(III) concentration without pre-concentration or pre-separation from chromium of other valences. The Cr(III) concentration may be measured using atomic absorption spectrometry, atomic emission spectrometry or atomic fluorescence spectrometry.

REFERENCES:
Reheulishvili A.N., Tsibakhashvili G.G. and Kaadze K.D., The Effect of the Chromium Valent State on the Results of Atomic Absorption and Atomic Fluorescent Spectroscopy of Chromium, (2001), Georgian Engineering News, 1, 118-122.
A. Reheulishvilli et al, Determination of the Content of Cr(VI) by the Method of Flame Atomic Absorption and Atomic Fluorescent Spectrometry (2002), Bulletin of the Georgian Academy of Sciences, 3, 501-504.
J. Posta, A. Gaspar, R. Toth, L. Ombodi, Cr(III) and Cr(VI) On-Line Preconcentration and High-Performance Flow Flame Emission Spectrometric Determination in Water Samples, (1996). Microchemical J., 54, 195-203.
J. Posta, A. Gaspar, T. Toth, L. Ombodi, Cr(III) and Cr(VI) On-Line Preconcentration and Determination with High Performance Flow Flame Emission Spectrometry in Natural Samples, (1996) Fresenius J. Anal. Chem, 355, 719-720.
A. Gaspar, J. Posta, On-line Sorption Preconcentration of Chromium(VI) and its Determination by Flame Atomic Absorption Spectrometry, (1997), Analitica Chimica Acta, 354, 151-158.
S. Tokahoglu, S. Kartal, L. Elci, Determination of Trace Metals in Waters by FAAS after Enrichment as Metal-HMDTC Complexes using Solid Phase Extraction, Bull. Korean Chem. Soc. (2002), vol. 23, No. 5, 693-698.
C. Sogor, A. Gaspar, J. Posta, Flame Atomic Absorption Spectrometric Determination of Total Chromium and Cr(VI) in Cigarette Ash and Smoke using Flow Injection/Hydraulic High-Pressure Sample Introduction, (1998), Microchemical Journal 58, 251-255.
A. Gaspar, S. Sogor, J. Posta, Possibilities for the simultaneous preconcentration and flame atomic absorption spectrometric determination of Cr(III) and Cr(VI) using a C18 column and sorption loop, (1999), Fresenius J. Anal. Chem., 363, 480.
A. Gaspar, J. Posta, R. Toth, On-line Chromatographic Separation and Determination of Chromium(III) and Chromium(VI) with Preconcentration of the Chromium(III) using Potassium Hydrogen Phtalate, in Various Samples by Flame Atomic Absorption Spectrometry, (1996), J. Anal. Atom. Spectrosc. vol. 11, 1067-1074.
J.Posta, A. Alimonti, F. Petrucci, S. Caroli, On-Line Separation and Preconcentration of Chromium Species in Seawater, (1996), Analytica Chimica Acta, 325, pp. 185-193.
Technical Report of the 8th Quarter—Project G-348, issued Sep. 30, 2002.

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