Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reexamination Certificate
2001-12-18
2003-11-25
Gupta, Yogendra N. (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S372000, C510S466000, C510S508000, C510S511000, C008S111000
Reexamination Certificate
active
06653264
ABSTRACT:
The present invention relates to a method for surface treatment of board based on biological fibrous material with an aqueous solution containing hydrogen peroxide, and to an aqueous solution particularly suitable for performing the method.
Board based on biological fibrous material is commonly used in the building industry because it has good mechanical properties, is easy to machine and work with, and can be prepared from renewable raw materials. However, for some applications the market demands bright colours, which in many cases is hard to obtain, depending on the raw materials used. Particularly, the board often has a brownish or yellowish colour and looks dirty.
It is an object of the present invention to provide a method for treating board based on biological fibrous material to obtain a surface with attractive appearance, preferably with a bright, non brownish and yellowish colour, most preferably looking like recently sawn lumber. It is another object of the invention to provide an environmental friendly method for treating board based on biological fibrous material that is easy to perform, and that does not damage the board. It is still another object of the invention to provide a composition particularly suitable for performing the method.
It has now been found that these objects can be achieved by a method as defined in the appended claims. Thus, the invention concerns a method for surface treatment of board based on biological fibrous material comprising a step of contacting the surface of said board based on biological fibrous material with an aqueous solution containing hydrogen peroxide. The aqueous solution preferably contains from about 1 to about 50 wt % H
2
O
2
, most preferably from about 5 to about 35 wt % H
2
O
2
.
The biological fibrous material used for the board may, for example, be wood or different kinds of grass, such as bagasse or straws of wheat. The board is normally produced by pressing fibres, strands, particles, wafers, sheets, or the like, of the biological fibrous material together with a binding agent. Various kinds binding agents can be used, for example duroplastic resin systems such as urea-formaldehyde, melamine-urea-formaldehyde, phenol-formaldehyde or isocyanate. It is also possible to use or thermoplastic binding agent, such as polyvinyl acrylate, polyvinyl acetate, polyethylene or polyvinyl chloride.
The invention is particularly favourable for treating wood based board, which in this context refers to board prepared by pressing wooden fibres, strands, particles, wafers, sheets, or the like, together with a binding agent, such as those mentioned above. Most kinds of wood can be used, hardwood as well as softwood, preferably having a density from about 350 to about 1000 kg/m
3
, such as spruce, pine, birch, aspen, red maple, rubber tree or marantii. Examples of commercially produced wood based boards that can be successfully treated according to the invention are particleboard, medium density fibre board (MDF), waferboard, oriented waferboard and oriented strand board (OSB). The method of the invention gives excellent result when OSB is treated. It is also possible to treat plywood with good results.
OSB is normally prepared from a resin and wooden strands, for example from about 10 to about 300 mm long and from about 2 to about 50 mm wide, lined up and arranged in about 3 to about 8 layers that are oriented at substantially right angles to one another. This gives a board with excellent mechanical properties, but unless its surface is treated according to the present invention, the visual appearance is still not satisfactory for many applications.
It has been found that better result and/or lower consumption of hydrogen peroxide is obtained if the aqueous solution for treating the board contains at least one surfactant, suitably in an amount from about 0.01 to about 20 wt %, preferably from about 0.1 to about 10 wt %, most preferably from about 0.1 to about 5 wt %. Particularly, it has been found that the presence of a surfactant in the aqueous solution decreases the risk for brownish or yellowish spots on the treated surface.
Preferred surfactants are compatible with hydrogen peroxide, which means that neither do they cause decomposition of the hydrogen peroxide, nor does the hydrogen peroxide cause decomposition of the surfactants. Further, the surfactant is preferably environmental friendly and biodegradable. Non-ionic surfactants are particularly preferred, but also amphoteric and/or an-ionic surfactants can be used.
Preferred non-ionic surfactants are selected from ethoxylated and/or propoxylated fatty acids, alcohols, phenols, amines or amides, preferably comprising from 1 to 15 most preferably from 4 to 8 moles ethylene oxide and from 0 to 5, preferably from 0 to 3 mols propylene oxide per mole acid, alcohol, phenol, amine or amide. Preferably the acid, alcohol, phenol, amine or amide comprises from 7 to 18, most preferably from 9 to 12 carbon atoms. Ethoxylated and optionally propoxylated alcohols are particularly preferred. Such surfactants are commercially available from Akzo Nobel under the trademarks Berol®048, Berol®185, Berol®266 and Berol®537.
It has also been found that both the visual appearance and the long term stability in UV light of the treated board, can be further improved if the aqueous solution contains a dispersion of at least one of solid silica or a solid metal oxide, such as an oxide of at least one of titanium, aluminium, antimony, tin, zirconium or cerium. The solution preferably contains from about 0.005 to about 10 wt % dispersed solid silica or metal oxide, most preferably from about 0.1 to about 5 wt % dispersed solid silica or metal oxide. However, unless used in combination with hydrogen peroxide, the silica or metal oxide does not give any effect.
The dispersion of silica or metal oxide is preferably in the form of a colloidal solution of dense, non-agglomerated particles, normally having a mean particle diameter from about 2 to about 500 nm, which corresponds to a specific surface from about 5 to about 1300 m
2
/gram. In order to obtain optimal stability of the treated board in UV light, the mean particle diameter of the silica or metal oxide is preferably from about 5 to about 400 nm, most preferably from about 10 to about 300 nm, which corresponds to a specific surface from about 500 to about 7 m
2
/gram, preferably from about 270 to about 10 m
2
/gram.
Colloidal silica is particularly useful as silica does not catalyse decomposition of hydrogen peroxide. Further, colloidal silica is commercially available in the form of stable aqueous silica sols that easily can be mixed with hydrogen peroxide solutions. Preferred aqueous silica sols are compatible with hydrogen peroxide, which means that neither do they cause decomposition of the hydrogen peroxide, nor does the hydrogen peroxide cause gelling of the silica. In one embodiment, an acidic silica sol is used, suitably having a pH, before addition to the hydrogen peroxide, from about 1 to about 7, preferably from about 2 to about 5. Particularly preferred acidic silica sols are cationic and contains silica particles that are surface modified with oxides or hydroxides of preferably polyvalent metals or other elements, such as at least one of aluminium, boron, titanium, antimony, tin, zirconium or cerium. Examples of silica sols of this kind commercially available from Eka Chemicals are Bindzil®CAT, Bindzil®CAT 80, Bindzil®CAT 220 and Bindzil®CAT 500. Other useful acidic silica sols are de-ionised sols, such Nyacol®2034 DI (Eka Chemicals).
In another embodiment, an alkaline silica sols is used, suitably with a pH, before addition to the hydrogen peroxide, from about 8 to about 11, preferably from about 8.5 to about 10.5. If an alkaline silica sol is used, it is preferably added in an amount so the pH of the resulting aqueous solution is not lower than about 3, most preferably not lower than about 4. Preferred alkaline silica sols are mainly stabilized with ammonium, such as Bindzil®15 NH
3
500 (Eka Chemicals), which minimises the deposition of
Hellström Pia
Nilsson Pär
Sundman Carl-Erik
Akzo Nobel N.V.
Gupta Yogendra N.
Petruncio John M
Serbin David J.
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