Method of treating polyolefin

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Treating polymer containing material or treating a solid...

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528483, 528491, 528494, 528495, 528496, 528502R, 528502F, 528503, C08F 602

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active

059902728

ABSTRACT:
A method of treating polyolefin comprises (i) a ligand-decomposition step of contacting polyolefin, which is obtained by the use of a transition metal compound containing ligands having cyclopentadienyl skeleton, with a ligand decomposer, such as water, oxygen, alcohol, alkylene oxide or peroxide, to decompose the ligands contained in the polyolefin, and (ii) a ligand-removal step of heating the polyolefin contacted with the ligand decomposer to remove the decomposed ligands from the polyolefin. According to this method, the residual ligands having cyclopentadienyl skeleton, which are contained in the polyolefin produced by the use of a transition metal compound containing ligands having cyclopentadienyl skeleton, are decomposed and removed from the polyolefin, whereby polyolefin diminished in odor development in the molding process can be obtained.

REFERENCES:
patent: 3931130 (1976-01-01), Beining
patent: 4029877 (1977-06-01), Yoshiura et al.
patent: 5340786 (1994-08-01), Tsutsui et al.
patent: 5387660 (1995-02-01), Doyle
patent: 5428127 (1995-06-01), Asanuma et al.
patent: 5498809 (1996-03-01), Emert et al.
Abstract of Japan Laid-Open Pat. Publ. No. 9-52918 (Feb. 25, 1997).

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