Method of synthesizing polymers from a solid electrolyte

Chemistry: electrical and wave energy – Processes and products

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204290R, 427 12, 4272556, 429111, C25C 300

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045444560

ABSTRACT:
A method of synthesizing electrically conductive polymers from a solvent-free solid polymer electrolyte wherein an assembly of a substrate having an electrode thereon, a thin coating of solid electrolyte including a solution of PEO complexed with an alkali salt, and a thin transparent noble metal electrode are disposed in an evacuated chamber into which a selected monomer vapor is introduced while an electric potential is applied across the solid electrolyte to hold the thin transparent electrode at a positive potential relative to the electrode on the substrate, whereby a highly conductive polymer film is grown on the transparent electrode between it and the solid electrolyte.

REFERENCES:
patent: 3574072 (1971-04-01), Louvar
patent: 4197171 (1980-04-01), Dunn
patent: 4401545 (1983-08-01), Naarmann
Skotheim, "Solid Polymer Electrolyte Photovoltaic Cell", J. Elect. Soc., 129: 894 (1982).
Skotheim, "Polypyrrole Electrodes . . . ", J. De Physique Collog., C3: 615 (1983).
Skotheim, "Solid Polymer Electrolyte Photoelectro Chemical Cells", BNL-34668 (1982).
Skotheim, "A Tandem Photovoltaic Cell . . . ", Appl. Physics Letter, 38: 712 (1981).

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