Method of synthesizing higher-molecular alcohol

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S902200

Reexamination Certificate

active

08080695

ABSTRACT:
The present invention provides a production method with which high molecular alcohols having an even number of carbon atoms such as 1-butanol, hexanol, octanol and decanol, and a mixture of these are efficiently collected through clean processes with the use of ethanol as a raw material. High molecular alcohols are produced from ethanol by using calcium phosphate-based compounds such as hydroxyapatite Ca10(PO4)6(OH)2, tricalcium phosphate Ca3(PO4)2, calcium monohydrogen phosphate CaHPO4.(0˜2)H2O, calcium diphosphate Ca2P2O7, octacalcium phosphate Ca8H2(PO4)6.5H2O, tetracalcium phosphate Ca4(PO4)2O or amorphous calcium phosphate Ca3(PO4)2. nH2O as a catalyst, using ethanol as a starting material, and setting a contact time at 0.4 second or longer.

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Mysov, V.M. et al. (2005). “Synthesis Gas Conversion Into Hydrocarbons (Gasoline Range) Over Bifunctional Zeolite-Containing Catalyst: Experimental Study and Mathematical Modelling,”Chemical Engineering Journal107:63-71.
Ndou, A.S. et al. (2003). “Dimerisation of Ethanol to Butanol Over Solid-Base Catalysts,”Applied Catalysis A: General251:337-345.
Yang, C. et al. (1993). “Bimolecular Condensation of Ethanol to 1-Butanol Catalyzed by Alkali Cation Zeolites,”Journal of Catalysis142:37-44.

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