Method of stabilizing solutions of chelated polyvalent metals

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

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423224, 423243, 4235731, 55 73, C01B 1704

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active

047848383

ABSTRACT:
A cyclic process for removing H.sub.2 S from a gaseous stream comprising contacting the gaseous stream with a solution of a chelated polyvalent metal to produce elemental sulfur, removing the elemental sulfur, and regenerating the reaction solution, e.g., by contacting it with oxygen, and recycling the regenerated solution to the reaction zone, is modified by introducing into the solution a free chelating agent. The introduction of the free chelating agent eliminates the loss of the polyvalent metal and the chelated polyvalent metal from the reaction solution.
There is also disclosed an aqueous reaction solution comprising a chelated polyvalent metal, sulfur, and a free chelating agent in the amount equal to at least about 0.1% by weight of the amount of the chelated polyvalent metal in the solution.

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