Method of stabilizing heavy metals in ash residues from combusti

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component

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4232421, 588256, C01B 2100, C01B 1700

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active

052846369

ABSTRACT:
A process for the stabilization of heavy metals in the ash produced by the combustion of a heavy metals containing fuel, such as municipal solid waste, by introducing into the combustion system a phosphorous oxide specie or elemental yellow phosphorus. The additive can be introduced at any point in the system upstream of the particulate removal device employed in the system. If elemental phosphorus is used, it must be introduced at a point in the system where it will be exposed to an elevated temperature and oxygen, so as to be converted to a phosphorus oxide specie. When elemental phosphorus is introduced into the system downstream of the combustion zone, it is also effective to reduce the NO content of the flue gas.

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"The SITE Demonstration of the CHEMFIX Solidification/Solidification Process at the Portable Equipment Salvage Company Site" Journal of Air Waste Management Association, E. F. Barth, Feb. 1990.
"Attenuation of Cd and Pb Solubility in Municipal Waste Incineration Ash" Soil Sci. Plant Anal., vol. 17, No. 4, pp. 385-392 (1986) Behel, et al.
"LBL PhosNOX Process for Combined Removal of SO.sub.2 and NO.sub.x from Flue Gas" 1991 Summer AIChE Summer National Meeting, Chang and Lee, Aug. 18, 1991.

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