Compositions: coating or plastic – Materials or ingredients – Pigment – filler – or aggregate compositions – e.g. – stone,...
Reexamination Certificate
1999-08-31
2001-09-04
Wu, David W. (Department: 1713)
Compositions: coating or plastic
Materials or ingredients
Pigment, filler, or aggregate compositions, e.g., stone,...
C524S501000, C524S522000, C524S523000
Reexamination Certificate
active
06284037
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to the use of an acrylate dispersion as an additive for aqueous coating formulations, said additive being particularly suitable for aqueous coating formulations and improving the stability of these coating materials in industrial plants.
BACKGROUND OF THE INVENTION
In the industrial coating of substrates, especially metal substrates, such as autobodies, vessels, etc., the coating systems are typically passed into the coating apparatus from stock tanks through systems of lines. If, for example, 2-component systems comprising coating material and curing agent are employed, these are led from separate stock tanks by way of so-called ring lines from which the components can be taken off at any desired point. In order to obtain uniform coating results it is necessary for the coating components to be applied to the substrate in defined amounts. Precise metering of the coating material, which is constant over the entire course of the procedure, can generally only be obtained if the consistency of the coating material as well, i.e. its viscosity and the homogeneous distribution of the individual coating components in the formulation, remains constant and any fluctuations in viscosity are minor.
In the course of transportation through the ring lines, the coating materials are exposed to high shear stress, which can in some cases result in changes in their viscosity, these changes then leading to a deterioration in the coating outcome.
SUMMARY OF THE INVENTION
The object on which the present invention is based was therefore to provide an additive for coating systems, especially aqueous coating systems, which improves the stability of coating materials which are led through industrial plants, especially by way of lines (ring lines).
The present invention provides for the use of a polymer dispersion as an additive for coating formulations, wherein the polymer dispersion comprises
(i) an acrylate polymer based on from 30 to 60% by weight of C
1
-C
8
-alkyl (meth)acrylate monomers, from 30 to 60% by weight of vinylaromatic monomers and from 0.5 to 10% by weight of (meth)acrylic acid, and
(ii) a nonassociative rheology stabilizer comprising an acrylate copolymer based on C
1
-C
6
-alkyl (meth)acrylate and (meth)acrylic acid.
The polymer dispersions used in accordance with the invention are outstandingly suitable as viscosity adjusters and as a stabilizer for coating formulations, especially for aqueous coating formulations, in order to improve the rheological stability of these coating materials. By adding the polymer dispersion employed in accordance with the invention it is possible to modify the viscosity behavior (Theological characteristics) of the coating systems in such a way that even prolonged stress to the coating materials as a result of shearing in the ring line produces no significant changes in viscosity which would lead to poor coating results.
It is also possible to add the polymer dispersion to coating formulations whose viscosity has already fallen to such a point that they can no longer be used in industrial plants. In such cases, the viscosity can be adjusted permanently to almost any desired level by adding the polymer dispersions.
The polymer dispersion used in accordance with the invention has been found particularly suitable as an addition to coating materials, such as metallic paints, for automotive finishing.
the polymer dispersion can be used as an additive for coating formulations in an amount, based on the solids content of the dispersion, of from 0.5 to 10% by weight, in particular from 0.5 to 5% by weight, based on the solids content of the coating formulation.
The acrylate polymer of component (i) that is employed in accordance with the invention can comprise as its C
1
-C
8
-alkyl (meth)acrylate monomer units the linear and branched-chain derivatives, preference being given to methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl and isopropyl (meth)acrylates, n-butyl and isobutyl (meth)acrylates, and 2-ethylhexyl (meth)acrylate. As further monomers, (meth)acrylamide monomers and derivatives thereof may also be present.
Examples of vinylaromatic monomers present as monomer units in the acrylate polymer of component (i) include styrene, &agr;-alkylstyrene and vinyltoluene.
The acrylate polymer can be prepared by techniques known from the prior art, an example being emulsion polymerization. The acrylate polymer is preferably employed in the form of a dispersion. During the preparation process, the ratio between the monomers and the water is preferably established such that the resultant dispersion has a solids content of from 30 to 60% by weight, preferably from 35 to 60% by weight, and can be used directly to prepare the basecoat composition. A particularly suitable acrylate polymer is obtainable commercially as an aqueous dispersion under the designation Acronal 290 D (BASF AG; Ludwigshafen).
To prepare a dispersion of the acrylate polymer, the emulsifier employed is preferably an anionic emulsifier, alone or in a mixture with others.
Examples of anionic emulsifiers are the alkali metal salts of sulfuric monoesters with alkylphenols or alcohols, and also the sulfuric monoesters of ethoxylated alkylphenols or ethoxylated alcohols, preferably the alkali metal salts of the sulfuric monoester of a nonylphenol which is reacted with from 4 to 5 mol of ethylene oxide per mol, alkyl- or arylsulfonates, sodium lauryl sulfate, sodium lauryl ethoxylate sulfate, and secondary sodium alkane sulfonates whose carbon chains contains 8-20 carbon atoms. The amount of the anionic emulsifier is from 0.1 to 5.0% by weight, based on the monomers, preferably from 0.5 to 3.0% by weight. Furthermore, in order to increase the stability of the aqueous dispersions it is possible to employ, additionally, a nonionic emulsifier of the type of an ethoxylated alkylphenol or fatty alcohol, e.g., an adduct of 1 mol of nonylphenol with from 4 to 30 mol of ethylene oxide, in a mixture with the anionic emulsifier.
The glass transition temperature of the acrylate polymer is preferably between 15° C. and 35° C., with particular preference between 20° C. and 25° C.
The acrylate polymer employed in accordance with the invention preferably as a number-average molecular mass (determined by gel permeation chromatography using polystyrene as standard) of from 200,000 to 2,000,000, preferably from 300,000 to 1,500,000.
As component (ii) in the basecoat composition, use is made, in accordance with the invention, of acrylate copolymers having groups that are nonassociative, said copolymers comprising C
1
-C
6
-alkyl (meth)acrylate and methacrylic acid as monomer units. A preferred copolymer comprises as its monomer units (meth)acrylic acid and at least two different C
1
-C
6
-alkyl (meth)acrylate monomers. Within the copolymer the (meth)acrylic acid is present preferably in amounts of from 40% by weight to 60% by weight, with particular preference from 46% by weight to 55% by weight, based on the amount of the overall copolymer. The first Cl-C6-alkyl (meth)acrylate monomer is present preferably in amounts of from 30% by weight to 50% by weight, in particular from 36% by weight to 46% by weight, and the second (meth)acrylate polymer preferably in amounts from 1% by weight to 10% by weight, in particular from 2% by weight to 8% by weight, based in each case on the amount of the overall copolymer. The rheological auxiliary is intended to give the basecoat composition the desired viscosity, especially at the pH employed, which is generally alkaline. A particularly preferred rheology stabilizer is, if present in the form of a dispersion, highly mobile in consistency but thickens at a neutral or basic pH. The acrylate copolymer is suitably employed as a finished dispersion. As emulsifiers, such dispersions preferably contain fatty alcohol alkoxylates, especially C
8
-C
22
-fatty alcohol ethoxylates. A particularly suitable acrylate copolymer dispersion is available commercially under the designation Viscalex HV 30 (Allied Corporation, Great Britain).
The rheol
BASF Coatings AG
Egwim K C
Wu David W.
LandOfFree
Method of stabilizing an aqueous coating composition does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Method of stabilizing an aqueous coating composition, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method of stabilizing an aqueous coating composition will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2474635