Method of simultaneously forming patterns on a die of an...

Semiconductor device manufacturing: process – Formation of electrically isolated lateral semiconductive... – Having substrate registration feature

Reexamination Certificate

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C257S797000

Reexamination Certificate

active

06391737

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of semiconductor patterning. More particularly, the present invention relates to a method of simultaneously forming patterns on a die of an alignment mark and other dies.
2. Description of the Related Art
Photolithography is a critical process that decides whether or not a semiconductor device can be successfully fabricated. Thus, photography occupies an important position in the semiconductor fabrication process. A common device fabrication process is taken as an example. Usually, according to the complexity of a device, a fabrication process needs 10 to 18 photolithography and exposure steps. In order to precisely transfer the pattern onto the chip, an alignment between layers needs to be performed before each photoresist exposure step. This is in order to avoid incorrect pattern transfer and the consequent chip disposal.
In a traditional exposure process, alignment mark is formed over the chip according to the location of a mask in order to achieve alignment. In order to avoid damage on the alignment mask during semiconductor fabrication, usually no pattern is formed around the alignment mark. However, this causes the oxide layer formed over the empty region around the alignment mark to remain to form a residual oxide layer after performance of chemical mechanical processing.
A fabrication process of a shallow trench isolation is taken as an example.
FIGS. 1A through 1C
are schematic cross-sectional views showing the progression of steps for producing a conventional shallow trench isolation structure.
As shown in
FIG. 1A
, a substrate
100
having alignment marks
102
thereon is provided. A mask layer
104
is formed over the substrate
100
, and then a photoresist layer
106
is formed over the mask layer
104
. Using the mask layer
104
as an etching mask, the mask layer
104
and a portion of the substrate
100
are removed to form a trench
108
in the substrate
100
.
As shown in
FIG. 1B
, the photoresist layer
106
is removed and then a silicon oxide layer
110
is formed over the substrate
100
so that the mask layer
104
is covered while the trench
108
is filled.
As shown in
FIG. 1C
, a chemical-mechanical polishing operation is carried out to remove redundant silicon oxide material from the silicon oxide layer
110
using the mask layer
104
as a polishing stop layer. Subsequently, a silicon oxide layer
110
a
is formed inside the trench
108
. Lastly, the mask layer
104
is removed.
In general, the density of trenches on a silicon chip is non-uniform and there are some empty regions on the silicon chip free of isolation structures. In the process of removing the oxide material above the mask layer
104
in a chemical-mechanical polishing operation, some of the oxide material above the empty region
112
will be retained to form a residual oxide layer
110
b.
To reduce thickness of the residual oxide film on top of empty regions, dummy isolation regions are sometimes formed over the empty regions
112
on the substrate
100
so that a uniform polish can be achieved.
FIGS. 2A through 2D
are schematic cross-sectional views showing the progression of steps for producing conventional shallow trench isolation structures and dummy isolation regions on empty regions in a substrate.
As shown in
FIG. 2A
, a photomask having both isolation region pattern
114
and dummy isolation region pattern
116
are used to pattern a photoresist layer
106
. After photo-exposure, the patterns are transferred to the photoresist layer
106
.
As shown in
FIG. 2B
, the photoresist layer
106
is developed. Hence, the isolation region pattern
114
and the dummy isolation region
116
are formed in the photoresist layer
106
. Using the photoresist layer
106
as an etching mask, the mask layer
104
and the substrate
100
are etched to form trenches
108
in the isolation region as well as dummy trenches
118
in the dummy isolation region.
As shown in
FIG. 2C
, the photoresist layer
106
is removed and then an oxide layer
110
is formed over the substrate
100
. Hence, the mask layer
104
is covered while the trenches
108
and the dummy trenches
118
are filled.
As shown in
FIG. 2D
, a chemical-mechanical polishing operation is carried out to remove any redundant oxide material above the mask layer
104
. The mask layer
104
is also removed to form isolation structures
110
a
and dummy isolation structures
110
c
in the substrate
100
.
In the aforementioned method, the isolation region pattern
114
and the dummy isolation pattern
116
are formed on the same photoresist layer
106
as shown in FIG.
2
A. In carrying out photo-exposure, a pattern on the photomask
400
in
FIG. 4
is transferred to each exposure shot
120
in the silicon chip
100
shown in
FIG. 3
one by one to form isolation region pattern
114
in the photoresist layer
106
above the substrate (silicon chip)
100
. Thereafter, the pattern of the photomask
400
is transferred onto the empty regions
112
around the alignment mark
102
. In this manner, the isolation region pattern
114
and the dummy isolation pattern
116
are formed on the same photoresist layer
106
.
As shown in
FIG. 3
, dimensions of shots
122
of the alignment marks
102
above the silicon chip are different from a dimension of the exposure shots
120
in each exposure operation. During an exposure process of dummy isolation region pattern, a corner
404
(for example, the left/upper corner) of the chromium film
402
on the photomask
400
in
FIG. 4
is aligned with a corner
130
(for example, the upper/left corner) of an alignment shot
122
. In addition, the non-transparent blade
300
of a stepper is used to block a portion of the area on the photomask
400
that corresponds to the alignment mark
102
and a portion of the alignment marking shot
122
. Because of the chromium film
402
on the photomask
400
and the non-transparent blade
300
of the stepper, light is permitted to pass in a specified region only. Consequently, trench pattern at the corner
404
of the photomask
400
is transferred to the corner
130
of shot
122
only. To form a complete dummy isolation pattern
116
, the photoresist layer
106
at the other corners of the alignment shot
122
must be transferred by carrying out similar steps.
The method demands a multiple of exposures to form a complete dummy isolation pattern
116
in the photoresist layer
106
above the alignment shot
122
. Consequently, throughput of the station decreases and wear of the non-transparent blades increases.
In general, the number of exposures can be reduced by placing the alignment mark to one side of the alignment shot rather than the middle and attaching neighboring alignment shots shot-to-shot as shown in the magnified view of FIG.
3
. However, by so doing, the chip areas surrounding such alignment marks are likely to be affected by subsequent polishing operations.
SUMMARY OF THE INVENTION
The invention is directed to a method of a forming semiconductor pattern. The method includes dividing a chip into a plurality of first exposure shots and a plurality of second exposure shots. After an alignment mark is formed in one of the dies of a first exposure shot, a waiting-for-patterning layer is formed over the chip. A negative photoresist layer is formed over the waiting-for-patterning layer. First exposure processes are carried out one-by-one to form a plurality of first exposed regions and a plurality of unexposed regions in the negative photoresist above the first exposure shots and the second exposure shots. A second exposure process is next carried out to form a second exposed region in the negative photoresist above the alignment mark. The second exposed region overlaps with the first exposed region and the unexposed region above the self-aligned mark and the overlapping region covers the alignment mark region. A photoresist development is carried out to remove the negative photoresist in the unexposed regions and expose the waiting-for-patterning la

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