Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy
Patent
1980-05-29
1983-06-07
Kyle, Deborah L.
Chemistry: electrical and wave energy
Processes and products
Processes of treating materials by wave energy
B01D 5900
Patent
active
043870104
ABSTRACT:
A method of separating and concentrating the .sup.15 N isotope from natural abundance nitric oxide (NO) comprising mixing natural abundance nitric oxide in an appropriate mole ratio with carbon dioxide (CO.sub.2); irradiating the NO--CO.sub.2 mixture with coherent laser light of a desired wavelength, thereby selectively exciting the nitric oxide species containing the .sup.15 N isotope, which subsequently reacts with the carbon dioxide to form nitrogen dioxide (.sup.15 NO.sub.2); and separating said nitrogen dioxide (.sup.15 NO.sub.2) from the gas mixture.
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Cohen et al., "Reaction of NO(A.sup.2 .SIGMA.+) with Carbon Dioxide", J. s. Chem. 71 (3) 558-63 (Feb. '67).
Lin, "A New Laser Photochemical Process for Isotope Enrichment", Spec. Lett. 8 (11) pp. 901-913 (1975).
Letokhov, "Photophysics and Photochemistry", Phys. Today, May 1977, pp. 23-32.
Basov et al., "Isotope Separation in Laser-Stimulated Chem. Reactions", JETP Lett. 20 (9) pp. 277-278 (1974).
Baronavski Andrew P.
McDonald Jimmie R.
Beers Robert F.
Ellis William T.
Kyle Deborah L.
The United States of America as represented by the Secretary of
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