Method of separating E and Z isomers of an alkene alcohol...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S917000, C568S918000

Reexamination Certificate

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11115359

ABSTRACT:
E and Z isomers of alkene alcohols and/or alkene alcohol derivatives are separated by substantially continuously contacting an ion exchange medium which is ion exchanged with silver and/or copper ions with the feed stream comprising the E and Z isomers of at least one alkene alcohol and/or at least one alkene alcohol derivative, then removing a product stream having a higher concentration of the E or Z isomer of at least one alkene alcohol or derivative of the alkene alcohol relative to the concentration of the E or Z isomer of the alkene alcohol or derivative of the alkene alcohol in the feed stream.

REFERENCES:
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patent: 4433195 (1984-02-01), Kulprathipanja
patent: 4443231 (1984-04-01), Siegell
patent: 5676826 (1997-10-01), Rossiter et al.
“Separation of Saturated, Unsaturated, and Acetylenic Fatty Acid Isomers by Silver Resin Chromatography” Journal of the American Oil Chemists' Society (1978), 55(7), pp. 5661-563.
Adlof, R. O. et al., J. Amer. Oil Chemists' Soc., vol. 57 (9), 1980, pp. 273-275, abstract only.
Emken, E. A. et al., J. Amer. Oil Chemists' Soc., vol. 41 (5), 1964, pp. 388-390, abstract only.
Warthen, J. David, Jr., J. of Chromatographic Science, vol. 14 (11), 1976, pp. 513-515, abstract only.
R. Adlof, et al., “Fractionation of cis- and trans-oleic, linoleic, and conjugated linoleic fatty acid methyl esters by silver Ion high-performance liquid chromatography”, Journal of Chromatography, vol. 799, No. 1-2, XP-004111398, Mar. 13, 1998, pp. 329-332.
Boryana Nikolova-Damyanova, et al., “Silver ion high-performance liquid chromatography of esters of isomeric octadecenoic fatty acids with short-chain monounsaturated alcohols”, Journal of Chromatography, vol. 693, No. 2, XP-004023453, Feb. 24, 1995, pp. 235-239.

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