Method of separating and recovering alkenylbenzenes and unreacte

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260668F, 260671A, C07C 352

Patent

active

039548953

ABSTRACT:
In the method wherein an alkenylation reaction product liquid obtained by the alkenylation reaction of an alkylbenzene and a C.sub.4 - C.sub.5 conjugated diene in the presence of alkali metal catalysts and containing unreacted alkylbenzene, alkali metal catalysts and organo-alkalimetal compounds is conveyed to a distillation zone at which said alkenylation reaction product liquid is separated by distillation to recover an alkenylbenzene-containing fraction and an unreacted alkylbenzene-containing fraction, the improvement which comprises adjusting the total of the concentrations of said alkali metal catalysts and organo-alkalimetal compounds in said alkenylation reaction product liquid introduced to the distillation zone so as to be 0.09 - 15 milligram atoms per kilogram of said product liquid, calculated as alkalimetal atoms, and thereafter conducting the distillation of said product liquid under conditions of non-addition of alcohols.

REFERENCES:
patent: 3766288 (1973-10-01), Shima et al.
patent: 3865889 (1975-02-01), Mitchell
patent: 3904702 (1975-09-01), Mitchell

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