Method of selectively inhibiting reaction between ions

Radiant energy – Ionic separation or analysis – Methods

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C250S288000, C250S281000, C250S283000, C250S292000, C250S489000, C436S086000

Reexamination Certificate

active

07064317

ABSTRACT:
A method of inhibiting the reaction between ions of opposite polarity is disclosed. The method includes exposing a population of ions to a resonance excitation frequency during a mass-to-charge altering reaction between a first subpopulation of ions and a second subpopulation of ions, the resonance excitation frequency being tuned to inhibit the mass-to-charge altering reaction between an ion of the first subpopulation of ions having a predetermined mass-to-charge ratio and an ion of the second subpopulation of ions so that when an ion of the first subpopulation of ions attains the predetermined mass-to-charge ratio, the ion having the predetermined mass-to-charge ratio is selectively inhibited from reacting with ions of the second subpopulation of ions.

REFERENCES:
patent: 6087658 (2000-07-01), Kawato
patent: 6674067 (2004-01-01), Grosshans et al.
patent: 0 793 256 (1997-09-01), None
Campbell, J.M.; Collings, B.A.; Douglas, D.J.; “A New Linear Ion Trap Time-of-flight System with Tandem Mass Spectrometry Capabilities,” Rapid Commun. Mass Spectrom., 12: 1463-1474; 1998.
Collings, B. A.; Campbell, J.M.; MAO, Dummin; Douglas, D. J.; “A combined linear ion trap time-of flight system with improved performance and MSncapabilities,” Rapid Commun. Mass Spectrom., 15: 1777-1795, 2001.
Marshall, Alan G.; Hendrickson, Christopher L.; Jackson, George S.; “Fourier Transform Ion Cyclotron Resonance Mass Spectrometry: A Primer,” Mass Spectromety Reviews, 17: 1-35, 1998.
Stephenson, James L., Jr.; Mcluckey, Scott A.; “Anion Effects on Storage and Resonance Ejection of High Mass-to-Charge Cations in Quadrupole Ion Trap Mass Spectrometry,” Anal. Chem. 69: 3760-3766; 1997.
R. E. March et al., “Practical Aspects of Ion Trap Mass Spectrometry”, Vol. 1—Fundamentals of Ion Trap Mass Spectrometry, Chapter 2—Theory of Quadrupole Mass Spectrometry,CRC Press, 1995, pp. 25-48.
R. E. March et al., “Practical Aspects of Ion Trap Mass Spectrometry”, vol. 1—Fundamentals of Ion Trap Mass Spectrometry, Chapter 3—Nonlinear Ion Traps,CRC Press, 1995, pp. 49-167.
R. E. March et al., “Practical Aspects of Ion Trap Mass Spectrometry”, vol. 1—Fundamentals of Ion Trap Mass Spectrometry, Chapter 4—Commercialization of the Quadrupole Ion Trap,CRC Press, 1995, pp. 169-205.
R. E. March et al., “Practical Aspects of Ion Trap Mass Spectrometry”, vol. II—Ion Trap Instrumentation, Chapter 1—High Mass, High Resolution Mass Spectrometry,CRC Press, 1995, pp. 3-47.
R. E. March et al., “Practical Aspects of Ion Trap Mass Spectrometry”, vol. II—Ion Trap Instrumentation, Chapter 3—Electrospray and the Quadrupole Ion Trap,CRC Press, 1995, pp. 89-141.
R. R. O. Loo et al., “A New Approach for the Study of Gas-Phase Ion-Ion Reactions Using Electrospray Ionization”,J. Am Soc. Mass Spectrom, 1992, vol. 3, pp. 695-705.
J. B. Fenn et al., “Electrospray Ionization for Mass Spectrometry of Large Biomolecules”,Science, 1989, vol. 246, No. 4926, pp. 64-71.
S. J. Gaskell, “Electrospray: Principles and Practice”,Journal of Mass Spectrometry, 1997, vol. 32, pp. 677-688.
J. F. Mahoney et al., “Massive Cluster Impact Mass Spectrometry: A New Desorption Method for the Analysis of Large Biomolecules”,Rapid Commun. Mass Spectrom, 1991, vol. 5, pp. 441-445.
M. Karas et al., “Laser Desorption Ionization of Proteins with Molecular Masses Exceeding 10000 Daltons”,Anal. Chem., 1988, vol. 60, No. 20, pp. 2299-2301.
M. Karas et al., “Ionization in matrix-assisted laser desorption/ionization: singly charged molecular ions are the lucky survivors”,J. Mass Spectrom, 2000, vol. 35, pp. 1-12.
J. L. Stephenson, Jr. et al., “Ion/Ion Proton Transfer Reactions for Protein Mixture Analysis”,Anal. Chem., 1996, vol. 68, No. 22, pp. 4026-4032.
J. L. Stephenson, Jr. et al., “Ion/Ion Reactions for Oligopeptide Mixture Analysis: Application to Mixtures Comprised of 0.5—100 kDa Components”,J. Am. Soc. Mass Spectrom, 1998, vol. 9, pp. 585-596.
J. L. Stephenson, Jr. et al., “Charge Manipulation for Improved Mass Determination of High-mass Species and Mixture Components by Electrospray Mass Spectrometry”,J. Mass Spectrom, 1998, vol. 33, pp. 664-672.
D. E. Clemmer et al., “Ion Mobility Measurements and their Applications to Clusters and Biomolecules”,Journal of Mass Spectrometry, 1997, vol. 32, pp. 577-592.
R. D. Smith et al., “Trapping, detection and reaction of very large single molecular ions by mass spectrometry”,Nature, 1994, vol. 369, pp. 137-139.
S. A. McLuckey etal., “Ion/Molecule Reactions for Improved Effective Mass Resolution in Electrospray Mass Spectrometry”,Anal. Chem., 1995, vol. 67, No. 14, pp. 2493-2497.
J. M. Wells et al., “Charge dependence protonated insulin decompositions”,International Journal of Mass Spectrometry, 2000, vol. 203, pp. 1-9.
S. A. McLuckey et al., “Charge Determination of Product Ions Formed from Collision-Induced Dissociation of Multiply Protonated Molecules via Ion/Molecule Reactions”,Anal. Chem., 1991, vol. 63, No. 18, pp. 1971-1978.
A. P. Hunter et al., “Proton-transfer Reactions of Mass-selected Multiply Charged Ions”,Rapid Communications in Mass Spectrometry, 1994, vol. 8, pp. 417-422.
S. A. McLuckey et al., “Novel quadrupole ion trap methods for characterizing the chemistry of gaseous macro-ions”,International Journal of Mass Spectrometry, 2000, vol. 200, pp. 137-161.
J. L. Stephenson, Jr., et al., “Gaseous Protein Cations Are Amphoteric”,J. Am. Chem. Soc., 1997, vol. 119, No. 7, pp. 1688-1696.
S. A. McLuckey et al., “Ion/Ion Proton-Transfer Kinetics: Implications for Analysis of Ions Derived from Electrospray of Protein Mixtures”,Anal. Chem., 1998, vol. 70, No. 6, pp. 1198-1202.
S. A. McLuckey et al., “Selective Ion Isolation/Rejection Over a Broad Mass Range in the Quadrupole Ion Trap”,J. Am. Soc. Mass Spectrom, 1991, vol. 2, pp. 11-21.
D. C. Muddiman et al., “Charge-State Reduction with Imrpoved Signal Intensity of Oligonucleotides in Electrospray Ionization Mass Spectrometry”,J. Am. Soc. Mass Spectrom, 1996, vol. 7, pp. 697-706.
S. A. McLuckey et al., “Reactions of Dimethylamine with Multiply Charged Ions of Cytochrome c”,J. Am. Chem. Soc., 1990, vol. 112, No. 14, pp. 5668-5670.
E. R. Williams, “Proton Transfer Reactivity of Large Multiply Charged Ions”,J. . Mass Spectrom, 1996, vol. 31, pp. 831-842.
R. R. O. Loo et al., “Protein Structural Effects in Gas Phase Ion/Molecule Reactions with Diethylamine”,Rapid Communications in Mass Spectrometry, 1992, vol. 6, pp. 159-165.
M. G. Ikonomou et al., “An ion source with which ions produced by electrospray can be subjected to ion/molecule reactions at intermediate pressures (10-100 Torr.) Deprotonation of polyprotonated peptides”,International Journal of Mass Spectrometry and Ion Processes, 1992, vol. 117, pp. 283-298.
B. E. Winger et al., “Gas-Phase Proton Transfer Reactions Involving Multiply Charged Cytochromeclons and Water Under Thermal Conditions”,J. Am. Soc. Mass Spectrom, 1992, vol. 3, pp. 624-630.
D. S. Gross, et al., “Experimental Measurement of Coulomb Energy and Intrinsic Dielectric Polarizability of a Multiply Protonated Peptide Ion Using Electrospray Ionization Fourier-Transform Mass Spectrometry”,J. Am. Chem. Soc., 1995, vol. 117, No. 3, pp. 883-890.
C. J. Cassady et al., “Elucidation of Isometric Structures for Ubiquitin [M + 12H]12+ Ions Produced by Electrospray Ionization Mass Spectrometry”,J. Mass Spectrom, 1996, vol. 31, pp. 247-254.
J. L. Stephenson, Jr. et al., “Ion/Ion Reactions in the Gas Phase: Proton Transfer Reactions Involving Multiply-Charged Proteins”,J. Am. Chem. Soc., 1996,

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Method of selectively inhibiting reaction between ions does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method of selectively inhibiting reaction between ions, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method of selectively inhibiting reaction between ions will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3640247

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.