Method of selective separation and concentration of gallium and/

Liquid purification or separation – Processes – Ion exchange or selective sorption

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210670, 210688, 423112, B01D 1504

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active

045170967

ABSTRACT:
A novel method is disclosed which enables gallium and/or indium to be selectively separated and concentrated from a solution containing them in very low concentrations together with many other metal ions in rather high concentrations. The solution is passed through a bed of a chelating ion exchange resin having an amino carboxylic acid group either immediately or after the pH adjustment. Gallium and/or indium adsorbed on the chelate resin is desorbed by eluting with a mineral acid. The eluate, after the pH adjustment, is passed through another bed of a chelating ion exchange resin having an amino carboxylic acid group, and the resin is treated with a mineral acid to elute the metal ions adsorbed on the resin to thereby recover gallium and/or indium in the form of a concentrated solution.

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patent: 4266045 (1981-05-01), Uejima et al.
patent: 4292284 (1981-09-01), Tomii et al.
patent: 4404174 (1983-09-01), Leveque et al.
patent: 4438078 (1984-03-01), Nalewajek

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