Method of selective reduction of halodisilanes with alkyltin hyd

Details Method of selective reduction of halodisilanes with alkyltin hyd Method of selective reduction of halodisilanes with alkyltin hyd

1987-12-28

1989-01-17

Doll, John

Chemistry of inorganic compounds

Silicon or compound thereof

Halogen containing

423341, C01B 3308

Patent

active

047987138

ABSTRACT:
The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.

REFERENCES:
patent: 3043857 (1962-07-01), Jenkner et al.
patent: 3378344 (1968-04-01), Horn et al.
patent: 3439008 (1969-04-01), Berger
patent: 4115426 (1978-09-01), Hiiro et al.
patent: 4617357 (1986-10-01), Pallie et al.
patent: 4639361 (1987-01-01), Aono et al.
Grady, et al, J. Org. Chem., vol. 37, pp. 2014-2016 (1969).
Wilt, et al., J. Am. Chem. Soc., vol. 105, pp. 5665-5675, (1983).

Affiliated with

Also associated with

Rating

Method of selective reduction of halodisilanes with alkyltin hyd does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Method of selective reduction of halodisilanes with alkyltin hyd, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Method of selective reduction of halodisilanes with alkyltin hyd will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-2413082