Metal working – Method of mechanical manufacture – Electrical device making
Reexamination Certificate
2000-05-01
2002-08-27
Kalafut, Stephen (Department: 1745)
Metal working
Method of mechanical manufacture
Electrical device making
C429S224000, C423S605000
Reexamination Certificate
active
06440181
ABSTRACT:
BACKGROUND
The invention relates to batteries.
Batteries, such as alkaline batteries, are commonly used electrical energy sources. Generally, a battery contains a negative electrode, typically called the anode, and a positive electrode, typically called the cathode. The anode contains an active material (e.g., zinc particles) that can be oxidized; and the cathode contains an active material (e.g., manganese dioxide) that can be reduced. The anode active material is capable of reducing the cathode active material. In order to prevent direct reaction of the anode material and the cathode material, the anode and the cathode are electrically isolated from each other by a separator.
When a battery is used as an electrical energy source in a device, such as a cellular telephone, electrical contact is made to the anode and the cathode, allowing electrons to flow through the device and permitting the respective oxidation and reduction reactions to occur to provide electrical power. An electrolyte in contact with the anode and the cathode contains ions that flow through the separator between the electrodes to maintain charge balance throughout the battery during discharge.
Some devices, such as digital cameras and cellular telephones, can demand high power from batteries. In such applications, it is desirable for the batteries, e.g., primary alkaline batteries, to have good performance and long lifetimes at high current discharge.
SUMMARY
The invention relates to a method of selecting manganese dioxide for high current discharge batteries. The method includes using stepped potential electrochemical spectroscopy (“SPECS”) to select the manganese dioxide. The SPECS results yield a dimensionless parameter, termed herein the “power coefficient”, which can be used to select a cathode material good for high current discharge.
Generally, the method of making a cathode includes determining a sample of manganese dioxide having a power coefficient greater than about 3.4, and incorporating the sample of manganese dioxide into the cathode. Preferably, the MnO
2
has a power coefficient greater than 3.6, preferably greater than about 3.8, and more preferably greater than about 4.0 or about 4.2. As used herein, manganese dioxide, or MnO
2
, refers to a “nominal” manganese dioxide, or MnO
2−x
, where 0≦x≦0.1. An example of manganese dioxide is gamma-MnO
2
, an intergrowth of pyrolusite and ramsdellite used in batteries.
The cathode can be incorporated into a battery. The battery can be a primary alkaline battery, a LeClanche cell, and a ZnCl
2
cell. The battery can include an anode having zinc as the active material.
Other features, objects, and advantages of the invention will be apparent from the drawings, description, and claims.
REFERENCES:
patent: 5569564 (1996-10-01), Swierbut et al.
patent: 6214198 (2001-04-01), Andersen et al.
patent: 0 964 467 A2 (1999-12-01), None
patent: WO 00/24071 (2000-04-01), None
Bowden et al., “Manganese Dioxide for Alkaline Zinc Batteries: Why Electrolytic MnO2”, ITE Letters on Batteries, vol. 1, No. 6, pp. 903-914, Nov. 2000.
Lavela et al., “Nickel-stabilized composite manganese oxides as lithium insertion elelctrodes”, Journal of Power Sources, vol. 84, No. 1, pp. 75-79, Nov. 1999.
Yves B. Chabre, “Step Potential Electrochemical Spectroscopy of Proton Intercalation in &Dgr;/&egr;-MnO2”, Journal of the Electrochemical Societ, vol. 138, No. 1, pp. 329-330, Jan. 1991.
A.H. Thompson, “Electrochemical Potential Spectroscopy: A New Electrochemical Measurement”J. Electrochem. Soc:Electrochemical Science and Technology vol. 126, No. 4:608-616 (1979). (No Month).
Y. Chabre and J. Pannetier, “Structural and Elecetrochemical Properties of the Proton / &ggr;-MnO2System”Prog. Solid st. Chem.: vol. 23.1-130 91995) (No Month).
Bowden William
Brandt Klaus
Cervera James J.
Choe Hyoun Sook
Sirotina Rimma A.
Crepeau Jonathan
Kalafut Stephen
The Gillette Company
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