Static structures (e.g. – buildings) – With means for split-prevention or damaged part repair
Reexamination Certificate
2002-11-07
2004-05-11
Wood, Elizabeth D. (Department: 1755)
Static structures (e.g., buildings)
With means for split-prevention or damaged part repair
C052S514500, C052S750000, C052S741300, C052S741400, C052S741410, C052S596000
Reexamination Certificate
active
06732482
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method of introducing into fresh concrete, as herein defined, compounds capable of sequestering chloride ions to establish resistance to corrosion of metal reinforcing elements contained within or contacting the concrete and provide a corrosion resistant oxide layer on the metal reinforcing elements, as well as related compositions and structures.
2. Description of the Prior Art
The advantageous use of metal reinforcing members, such as steel reinforcing members, in concrete for structural uses has been known for many years. Concrete is known to provide desired compressive strength, but tends to lack tensile strength. The reinforcing bars co-act with the concrete to provide enhanced tensile for the combination of materials. It has also been known to employ corrugated metal deck in combination with concrete to create a composite with similar benefits. Numerous other metal members have been embedded in concrete or provided in contact therewith to achieve enhanced benefits in the structural environment as a result of such materials. Among these additional materials are grids, beams, bolts, hold-downs and wire mesh.
One problem with such construction has arisen as a result of exposure of concrete to salts, such as calcium chloride and sodium chloride, on external structural members to resist the undesired accumulation of snow and ice on bridges and other concrete paved areas such as roadways, parking lots, sidewalks and the like. While these chloride salts do provide benefits in terms of de-icing of concrete surfaces, they frequently result in the chloride solutions migrating into the concrete decks and adjacent vertical concrete surfaces, such as walls and columns, also subjecting these to chloride intrusion. Also, saline seawater may migrate into the pores of concrete exposed to seawater as in sea walls, With respect to bridge decks, in particular, an enhanced problem results from air movement under the deck creating an environment wherein the salts are aspirated into the concrete and salt laden solutions flow into the pores.
Regardless of the manner in which chloride enters such concrete, the chloride, upon reaching the steel reinforcing members, tends to accelerate corrosion of the same because the oxidation of the metal metallic iron to Fe
2+
is catalyzed by the chloride. Also, oxides and hydroxides of Fe
2+
frequently form and occupy porosity in the vicinity of the interface of the steel and concrete. In addition, oxides and hydroxides of Fe
3+
may also be produced. As these iron oxides and hydroxides are of greater volume than the iron metal from which they were produced, they tend to cause internal stresses which may become high enough to crack the concrete, and also degrade the desired bond between the metal reinforcing elements and the concrete.
It has been known to employ nitrites, such as calcium nitrite, in resisting corrosion of steel parts in concrete. It is believed that the nitrites oxidize the Fe
2+
to Fe
3+
which, in turn, precipitates as Fe
2
O
3
. The Fe
2
O
3
thus formed tends to act as a barrier to further contact between the chloride and the steel. See, generally, U.S. Pat. Nos. 4,092,109 and 4,285,733. Neither calcium nitrate nor Fe
2
O
3
, however, function to sequester chloride. The latter provides merely a barrier.
There remains, therefore, a very real and substantial need for a method and related composition and structure which will resist undesired corrosion of metal structural elements contained within, or in contact with, concrete structural members.
SUMMARY OF THE INVENTION
The present invention has met the above-described need.
The method, in one embodiment, includes resisting corrosion in concrete containing metal reinforcing elements composed of steel, copper, galvanized steel, tin plated steel or other structurally suitable metals by introducing into fresh concrete containing metal reinforcing elements at least one compound capable of sequestering chloride ions in a low solubility compound.
In connection with steel reinforcing elements, a low solubility compound within which the chloride ions are sequestered preferably also is created in a reaction that releases nitrite, which serves to oxidize Fe
2+
to thereby provide a corrosion-resisting oxide layer on the steel reinforcing elements. This, therefore, in connection with steel achieves two levels of corrosion resistance, one of which is the actual capturing or sequestering of the potentially damaging chloride ions, and the second of which provides a protective layer on the metal reinforcing elements.
Among the preferred compounds for use in the method of the present invention are one or more compounds selected from the group consisting of 3CaO·Al
2
O
3
·Ca(NO
2
)
2
·nH
2
O; 3CaO·Al
2
O
3
·Ca(NO
3
)
2
·nH
2
O; and 3CaO·Fe
2
O
3
·Ca(NO
2
)
2
·nH
2
O; wherein n=0 to 18 and preferably 10 to 18, depending upon the relative humidity to which a compound is equilibrated. If desired, lower values of “n” may be obtained by drying at low relative humidity as by evacuation or by heating, for example.
A further compound employed in another embodiment of the invention is, 3Me(II)O·R
2
O
3
·Me(II)(anion)
2
·nH
2
O wherein Me(II) is one or more divalent cations, such as Ca for example, R
2
is Al
2
, Fe
2
or Cr
2
anion is NO
2
, NO
3
, CO
3
, BO
4
or OH and n is 0 to 24, and preferably 10 to 24. For some formulations, the anion may be divalent. In this case the formula would be Me(II)O·R
2
O
3
·Me(II)(anion)nH
2
O wherein n is 0 to 18 and preferably 10 to 18.
The invention also contemplates a concrete structure which has hydrated fresh concrete and a plurality of metal structural elements in contact with the hydrated fresh concrete with a compound which sequesters chloride ions dispersed within the concrete.
It is an object of the present invention to provide a method and related compounds and structures for inhibiting corrosion of metal elements positioned within or in contact with concrete in a structural environment.
It is a further object of the present invention to provide such a system wherein undesired chloride ions will, as a result of a reaction, be sequestered, thereby reducing their ability to corrode the metal elements.
It is yet another object of the invention to, through a reaction effecting such sequestration of ions, to provide free nitrites which will oxidize the Fe
2+
to a Fe
3+
ion which, in turn, precipitates as Fe
2
O
3
which coats the metal element and, thereby, resists corrosion.
It is yet another object of the present invention to provide such a system which employs unique compounds.
It is another object of the present invention to provide such a system which will effectively and rapidly provide corrosion resistance to steel and other metals.
It is yet another object of the invention to provide such a system which may be employed by merely adding one or more compounds of choice to fresh concrete without requiring substantial changes in conventional practices employed in producing and placing the concrete structure.
These and other objects of the invention will be more fully understood from the following description of the invention with reference to the drawings appended hereto.
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patent: 4092109 (1978-05-01), Rosenberg et al.
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patent: 5127954 (1992-07-01), Johnston et al.
patent: 5198082 (1993-03-01), Vennesland et al.
patent: 5422141 (1995-06-01), Hoopes et al.
patent: 5435846 (1995-07-01), Tatematsu et al.
patent: 5597514 (1997-01-01), Miksic et al.
patent: 5634966 (1997-06-01), Berke et al.
patent: 6402990 (2002-06-01), Marazzani et al.
patent: 1258473 (1989-08-01), None
patent: 09286652 (1996-02-01), None
patent: 9-286652 (1997-01-01), None
patent: 09049796 (1998-09-01), None
Cements Research Progress 1989, The American Ceramic Society, pp. 137, 148-155.
Cemen
Anderson Debra Z.
Eckert Seamans Cherin & Mellott , LLC
Silverman Arnold B.
Wood Elizabeth D.
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