Method of removing trace quantities of alkali metal impurities f

Coating processes – Electrical product produced – Photoelectric

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4273833, 445 11, 445 13, 445 17, H01J 4016

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045685673

ABSTRACT:
A method of processing a bialkali-antimonide photoemissive cathode to remove trace quantities of alkali metal impurities is disclosed. The cathode is formed by heating alkali vapor sources comprising the chromates of two alkali materials which include trace impurities of two other alkali materials of higher vapor pressures than the aforementioned two alkali materials to sufficiently high temperatures to produce alkali vapors. The temperature of the substrate onto which the various alkali vapors condense is maintained at a sufficiently high temperature for a sufficiently long period of time to drive off the trace quantities of the higher vapor pressure other alkali materials from the substrate. Additionally, after the alkali vapor sources are heated to temperatures sufficient to vaporize the alkali chromates therein, the temperatures of the sources are lower and maintained at sufficient levels to accelerate the removal of reduced alkali vapors from the sources and from the photomultiplier tube.

REFERENCES:
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patent: 2676282 (1954-04-01), Polkosky
patent: 2770561 (1956-11-01), Sommer
patent: 2877078 (1959-03-01), Gauthier
patent: 2914690 (1959-11-01), Sommer
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patent: 4376246 (1983-03-01), Butterwick
A. Sommer, Photoemissive Materials, Wiley and Sons, Inc., 1968, pp. 113-124.
Electron Tube Division, RCA Corporation, Electron Tube Design, pp. 366-369, (1962).

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