Method of removing sulfur emissions from a fluidized-bed combust

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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252190, 252463, B01J 800, C01B 1700, B01J 2308, C09K 300

Patent

active

040910768

ABSTRACT:
Alkali metal or alkaline earth metal oxides are impregnated within refractory support material such as alumina and introduced into a fluidized-bed process for the combustion of coal. Sulfur dioxide produced during combustion reacts with the metal oxide to form metal sulfates within the porous support material. The support material is removed from the process and the metal sulfate regenerated to metal oxide by chemical reduction. Suitable pore sizes are originally developed within the support material by heat-treating to accommodate both the sulfation and regeneration while still maintaining good particle strength.

REFERENCES:
patent: 931515 (1909-08-01), Sprague
patent: 2698305 (1954-12-01), Plank et al.
patent: 2992884 (1961-07-01), Bienstock et al.
patent: 3070639 (1962-12-01), Geerts et al.
patent: 3411865 (1968-11-01), Pijpers et al.
Alumina Properties, Russell et al., 1956, p. 37.

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