Method of removing sulfur dioxide from a flue gas stream

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

Reexamination Certificate

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C423S243080, C423S244010, C423S244070, C423S244080

Reexamination Certificate

active

07854911

ABSTRACT:
A method of removing SOxfrom a flue gas stream including SOxincludes providing a source of trona and injecting the trona as a dry sorbent into the flue gas stream. The temperature of the flue gas is at an elevated temperature greater than 400° F., preferably between about 600° F. and about 900° F. The trona is maintained in contact with the flue gas for a time sufficient to react a portion of the trona with a portion of the SOxto reduce the concentration of the SO2and/or SO3in the flue gas stream.

REFERENCES:
patent: 3524720 (1970-08-01), Bauer
patent: 3704569 (1972-12-01), Hardison et al.
patent: 3709977 (1973-01-01), Villiers-Fisher
patent: 3722178 (1973-03-01), Aaland et al.
patent: 3833711 (1974-09-01), Villiers-Fisher
patent: 3846535 (1974-11-01), Fonseca
patent: 3868444 (1975-02-01), Frevel et al.
patent: 3869538 (1975-03-01), Sproul et al.
patent: 3880629 (1975-04-01), Dulin et al.
patent: 3932587 (1976-01-01), Grantham et al.
patent: 3932588 (1976-01-01), Libutti et al.
patent: 3966878 (1976-06-01), Pausch et al.
patent: 3984296 (1976-10-01), Richards
patent: 4001384 (1977-01-01), Iwakura et al.
patent: 4021526 (1977-05-01), Gancy et al.
patent: 4034063 (1977-07-01), Rosar et al.
patent: 4105744 (1978-08-01), Erdoess et al.
patent: 4113447 (1978-09-01), Bennett et al.
patent: 4185080 (1980-01-01), Rechmeier
patent: 4197278 (1980-04-01), Gehri et al.
patent: 4198380 (1980-04-01), Kohl
patent: 4208192 (1980-06-01), Quigley et al.
patent: 4208386 (1980-06-01), Arand et al.
patent: 4220478 (1980-09-01), Schuff
patent: 4244930 (1981-01-01), Weber
patent: 4273750 (1981-06-01), Hollett, Jr. et al.
patent: 4306885 (1981-12-01), Kober et al.
patent: 4325924 (1982-04-01), Arand et al.
patent: 4352747 (1982-10-01), Every et al.
patent: 4385039 (1983-05-01), Lowell et al.
patent: 4391207 (1983-07-01), Petersen
patent: 4439351 (1984-03-01), Sinha
patent: 4481172 (1984-11-01), Lowell et al.
patent: 4504451 (1985-03-01), Quee et al.
patent: 4533364 (1985-08-01), Altman et al.
patent: 4540554 (1985-09-01), Dayen
patent: 4547351 (1985-10-01), Im et al.
patent: 4555391 (1985-11-01), Cyran et al.
patent: 4559211 (1985-12-01), Feldman et al.
patent: 4588569 (1986-05-01), Cyran et al.
patent: 4609539 (1986-09-01), Horecky et al.
patent: 4620856 (1986-11-01), Rosenberg et al.
patent: 4629545 (1986-12-01), Mani et al.
patent: 4645652 (1987-02-01), Kimura
patent: 4663136 (1987-05-01), Furlong
patent: 4664893 (1987-05-01), Sarapata et al.
patent: 4726710 (1988-02-01), Rosar et al.
patent: 4731233 (1988-03-01), Thompson et al.
patent: 4738690 (1988-04-01), Radway et al.
patent: 4743439 (1988-05-01), Ready
patent: 4780290 (1988-10-01), Curtius
patent: 4783325 (1988-11-01), Jones
patent: 4795586 (1989-01-01), Thompson et al.
patent: 4795619 (1989-01-01), Lerner
patent: 4810478 (1989-03-01), Graf
patent: 4839147 (1989-06-01), Lindbauer et al.
patent: 4844915 (1989-07-01), Hooper
patent: 4853194 (1989-08-01), Hino et al.
patent: 4859438 (1989-08-01), Lindbauer et al.
patent: 4871522 (1989-10-01), Doyle
patent: 4872887 (1989-10-01), Altman et al.
patent: 4917875 (1990-04-01), Moore et al.
patent: 4921886 (1990-05-01), Ewan et al.
patent: 4940569 (1990-07-01), Neal et al.
patent: 4946311 (1990-08-01), Rosar et al.
patent: 4954324 (1990-09-01), Hooper et al.
patent: 4960445 (1990-10-01), Helfritch et al.
patent: 4960577 (1990-10-01), Torbov et al.
patent: 4966610 (1990-10-01), Krigmont et al.
patent: 4973459 (1990-11-01), Lippert et al.
patent: 4975257 (1990-12-01), Lin
patent: 4987839 (1991-01-01), Krigmont et al.
patent: 5002741 (1991-03-01), Hooper et al.
patent: 5034114 (1991-07-01), Kukin
patent: 5074226 (1991-12-01), Lynch
patent: 5082586 (1992-01-01), Hooper
patent: 5118480 (1992-06-01), Cook et al.
patent: 5120508 (1992-06-01), Jones
patent: 5165902 (1992-11-01), Bortz et al.
patent: 5165903 (1992-11-01), Hunt et al.
patent: 5219536 (1993-06-01), Pinnavaia et al.
patent: 5284637 (1994-02-01), Merritt et al.
patent: 5346674 (1994-09-01), Weinwurm et al.
patent: 5470556 (1995-11-01), Samish
patent: 5540902 (1996-07-01), De Soete
patent: 5582807 (1996-12-01), Liao et al.
patent: 5585081 (1996-12-01), Chu et al.
patent: 5591249 (1997-01-01), Hankins
patent: 5591412 (1997-01-01), Jones et al.
patent: 5591417 (1997-01-01), Buchanan et al.
patent: 5599508 (1997-02-01), Martinelli
patent: 5658547 (1997-08-01), Michalak et al.
patent: 5678493 (1997-10-01), Kelley et al.
patent: 5872887 (1999-02-01), Walker et al.
patent: 5879433 (1999-03-01), Gallup et al.
patent: 5935539 (1999-08-01), Depelsenaire
patent: 5938818 (1999-08-01), Miller
patent: 5961837 (1999-10-01), Ferrara et al.
patent: 6001152 (1999-12-01), Sinha
patent: 6033639 (2000-03-01), Odenmo
patent: 6117405 (2000-09-01), Frey et al.
patent: 6126910 (2000-10-01), Wilhelm et al.
patent: 6143263 (2000-11-01), Johnson et al.
patent: 6168709 (2001-01-01), Etter
patent: 6180074 (2001-01-01), Fourcot et al.
patent: 6214308 (2001-04-01), Keener et al.
patent: 6267802 (2001-07-01), Baldrey et al.
patent: 6270555 (2001-08-01), Wood et al.
patent: 6290872 (2001-09-01), Fourcot et al.
patent: 6303083 (2001-10-01), Johnson et al.
patent: 6352653 (2002-03-01), Hirano et al.
patent: 6490984 (2002-12-01), Moriya et al.
patent: 6522994 (2003-02-01), Lang
patent: 6722295 (2004-04-01), Zauderer
patent: 6780385 (2004-08-01), Sakurai et al.
patent: 6797035 (2004-09-01), Baldrey et al.
patent: 6803025 (2004-10-01), Meserole et al.
patent: 7022296 (2006-04-01), Khang et al.
patent: 7481987 (2009-01-01), Maziuk, Jr.
patent: 7531154 (2009-05-01), Maziuk, Jr.
patent: 2002/0001556 (2002-01-01), Sakurai et al.
patent: 2002/0054846 (2002-05-01), Fagiolini et al.
patent: 2002/0061271 (2002-05-01), Zauderer
patent: 2004/0040438 (2004-03-01), Baldrey et al.
patent: 2005/0201914 (2005-09-01), Ritzenthaler
patent: 2005/0255605 (2005-11-01), Muzio et al.
patent: 2005/0260114 (2005-11-01), Higgins et al.
patent: 2006/0034743 (2006-02-01), Radway et al.
patent: 2007/0081936 (2007-04-01), Maziuk
patent: 2007/0243121 (2007-10-01), Rogan
patent: 0 170 355 (1986-02-01), None
patent: 0 309 848 (1989-04-01), None
patent: 1004345 (2000-05-01), None
patent: 2106489 (1983-04-01), None
patent: 63 175652 (1998-07-01), None
patent: WO 93/14026 (1993-07-01), None
patent: WO 02/08666 (2002-01-01), None
patent: WO 2007/031552 (2007-03-01), None
“Integrated Dry NOx/SO2 Emissions Control System A DOE Assessment” published by the U. S. Dept. of Energy, Oct. 2001, DOE/NETL-2002/1160, pp. 1-47.
“Successful Mitigation of SO3 Emissions While Simultaneously Enhancing ESP Operation at the General James M. Gavin Plant in Cheshire, Ohio by Employing Dry Sorbent Injection of Trona Upstream of the ESP” by Douglas P. Ritzenthaler et al., Aug. 31, 2004, Paper No. 8, Mega Symposium 2004, pp. 1-15.
“Bench-Scale Study of the Dry Removal of SO2 With Nahcolite and Trona” prepared by KVP, Inc., CS-1744 Research Project 982-8, Mar. 1981, pp. S-2, S-3, S-8, S-9 and S-10.
Solvay Chemicals Technical Publication “Trona Use in Dry Sodium Injection for Acid Gas Removal” copyrighted 2005, pp. 1-8 to 8-8.
“Trona Use in Dry Sodium Injection for Acid Gas Removal”; Solvay Chemicals Technical Publication; Solvay Chemicals, Inc. 2005.
“Clean Coal Technology”; Technologies for the Combined Control of Sulfur Dioxide and Nitrogen Oxides Emissions from Coal-Fired Boilers; a report on three projects conducted under separate cooperative agreements between: U.S. Department of Energy and—ABB Environmental Systems,—The Babcock & Wilcox Company,—Public Service Company of Colorado; 25pp; May 1999.
Andrea B. Baldwin; “Trona Use in Dry Sodium Injection for Acid Gas Removal”; Solvay Minerals, Inc.; Houston, TX (date unknown).
DOE/NETL-2002/1160 “Integrated Dry NOx/SO2 Emissions Control System A DOE Assessment”, U.S. Department of Energy and National Energy Technology Laboratory; 47 pp; Oct. 2001.
Douglas P. Ritzenthaler et al.; “Successful Mitigation of SO3Emissions While Simultaneous

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