Method of removing silicon from waste hydrochloric acid pickling

Chemistry of inorganic compounds – Silicon or compound thereof – Oxygen containing

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423DIG1, 210738, C01B 33037

Patent

active

050323695

ABSTRACT:
A method of removing silicon from a waste hydrochloric acid pickling solution is disclosed which comprises stirring the waste solution long enough to form a sludge having a particle size such that the sludge can be separated by a conventional means such as filtration through a filter of at least 0.1 .mu.m in pore diameter, centrifugation or sedimentation. The stirring period can be greatly reduced by adding to the waste pickling solution sludge recovered from an aged waste hydrochloric acid pickling solution or a carbonaceous material such as carbon black having hydrophilic groups on the surface. The sludge is also useful as a filter medium in filtration of the waste pickling solution to remove silicon. The present method can decrease the silicon content to 0.01% or less in terms of converted SiO.sub.2 /Fe.sub.2 O.sub.3 weight ratio.

REFERENCES:
Hackh's Chemical Dictionary, Fourth Edition, Grant ed., p. 133.

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