Method of removing Pu(IV) polymer from nuclear fuel reclaiming l

Chemistry: electrical and wave energy – Processes and products

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204140, 423 3, 423251, C25C 122, C01G 5600, C01G 5700

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active

043167764

ABSTRACT:
A Pu(IV) polymer not extractable from a nuclear fuel reclaiming solution by conventional processes is electrolytically converted to Pu.sup.3+ and PuO.sub.2.sup.2+ ions which are subsequently converted to Pu.sup.4+ ions extractable by the conventional processes.

REFERENCES:
The Preparation and Properties of Some Plutonium Compounds, Part V, Colloidal Quadivalent Plutonium, J. Chem. Soc., p. 3358, 1956, by Ockenden and Welch.
Hazards and Experimental Procedure Evaluation For: Studies on the Polymerization and Hydrolysis of Plutonium in Uranyl Nitrate and Nitric Acid Solutions at Elevated Temperatures, published in 1963 by Biggers and Costanzo.
A Study of the Polymerization, Depolymerization, and Precipitation of Tetravalent Plutonium as Functions of Temperature and Acidity by Spectrophotometric Methods: Preliminary Report, published in 1963 by Beggers and Costanzo.
Plutonium Handbook, A Guide to the Technology, vol. 1, section 13-2.2, published in 1967 by Gordon and Breach, Science Publishers.

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