Method of removing formyl groups from N-formyl-amino acid and N-

Details Method of removing formyl groups from N-formyl-amino acid and N- Method of removing formyl groups from N-formyl-amino acid and N-

1975-11-26

1977-05-03

Gotts, Lewis

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603096, 2603131, 26032614T, 260468J, 260468K, 260471R, 260471A, 260481R, 260482R, 260482P, C07G 700, C07C10352

Patent

active

040214184

ABSTRACT:
The masking N-formyl group of an N-formyl-amino acid ester or N-formyl-peptide ester is removed without major side reactions when the ester is reacted in an inert liquid medium with hydroxylamine of which at least 70% is present in the form of a salt with a strong acid, the remainder, if any, being present as the free base or the salt of a weak acid.

REFERENCES:
geiger et al., Chem. Ber., 101, 3386-3391 (1968).

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