Method of removing and crystallizing cation resin absorbed calci

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ion-exchange polymer or process of preparing

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210669, 210677, 210687, C08J 520, B01J 4900

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active

050212168

ABSTRACT:
An improved method is provided for regenerating cation exchange resin loaded with metal ion impurities from wet process phosphoric acid. A regenerant solution is used composed of a mixture of ammonium sulfate and sulfuric acid in predetermined proportions which are maintained during recycle of the regenerant. This solution is preferably formed from anhydrous ammonia and sulfuric acid. Calcium and magnesium sulfates are selectively crystallized from the regenerant solution in the form of readily filterable crystals.

REFERENCES:
patent: 4363880 (1982-12-01), Whitney
patent: 4385993 (1983-05-01), Hedrick et al.
patent: 4493907 (1985-01-01), Hedrick et al.
patent: 4652352 (1987-03-01), Saieva
patent: 4721519 (1988-01-01), Thomas et al.
patent: 4861490 (1989-08-01), Morris
"industrial Scale-Up of a Phosphoric Acid Purification Process", by James E. Van Wyk, Nov. 11, 1986, American Institute of Chemical Engineers.

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