Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1981-01-26
1982-11-16
Konopka, P. E.
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
252420, 252435, 562599, B01J 2728, B01J 2718, C07C 51377, C07C 5705
Patent
active
043594018
ABSTRACT:
A method of regenerating an iron/phosphate-type catalyst typically used for the oxydehydrogenation of lower molecular weight carboncylic acids comprising the step of subjecting the catalyst to an oxidizing atmosphere, preferably by discontinuing the flow of organic feed through the catalyst bed, followed by the step of subjecting the catalyst to a reducing atmosphere, preferably injecting organic feed in the absence of oxygen over the catalyst. The method is specifically described with respect to the production of methacrylic acid by the oxydehydrogenation of isobutyric acid.
REFERENCES:
patent: 3315006 (1967-04-01), Alexander et al.
patent: 3398100 (1968-08-01), Christman
patent: 3634494 (1972-01-01), Tsu
patent: 3948959 (1976-04-01), Cavaterra et al.
patent: 4010114 (1977-03-01), Walker et al.
patent: 4176234 (1979-11-01), Grasselli
Ashland Oil Inc.
Konopka P. E.
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