Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Nitrogen or nitrogenous component
Patent
1992-08-11
1994-12-27
Straub, Gary P.
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Nitrogen or nitrogenous component
423241, 423240S, 588248, 239 21, 239 141, B01D 5334
Patent
active
053763467
ABSTRACT:
By reaction of Cl and ClO radicals with alkaline cations, such as K.sub.2 O.sub.2, Na.sub.2 O.sub.2, CaO, CaO . MgO, Ca(OH).sub.2, CaCO.sub.3, (Ca Mg) (CO.sub.3).sub.3, Na.sub.2 CO.sub.3, NaHCO.sub.3 and NaHCO.sub.3 . Na.sub.2 CO.sub.3 . 2 H.sub.2 O, these radicals are either bound in ultraviolet radiation stable crystalline inorganic lattices or in high stability alkaline salt solutions. Since most of these salts are hygroscopic, they are able to pick up water vapor from the atmosphere, increase in size, and fall through the stratosphere and troposphere resulting in a faster removal rate than would otherwise occur.
REFERENCES:
patent: 2408696 (1946-10-01), Smallwood
patent: 3289409 (1966-12-01), Schirmer
patent: 5147429 (1992-09-01), Bartholomew et al.
Murad et al. Nature 289 N5795 pp. 273-274 (1981) Jan. 1981 Possible role for metals in stratosphere chlorine chemistry.
Hendrickson Stuart L.
Straub Gary P.
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