Method of recovering gallium from scrap containing gallium

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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75 62, 75 63, 210180, 210774, 423 87, 423 88, 423126, 423127, 423136, 423491, 423495, C25C 100

Patent

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046665757

ABSTRACT:
Scrap containing gallium and arsenic is treated with chlorine gas to form a crude gallium and arsenic chloride mixture. Arsenic chloride and impurities having a lower boiling point than that of arsenic chloride are removed from the mixture by vaporization so that crude gallium chloride may be obtained. The crude gallium chloride is purified by distillation. The purified gallium chloride is electrolyzed to yield metallic gallium. If the scrap has a molar gallium/arsenic ratio exceeding 1, arsenic chloride or metallic arsenic or both are added to the scrap before it if treated with chlorine gas.

REFERENCES:
patent: 4368108 (1983-01-01), Rubinshtein
patent: 4421615 (1983-12-01), Yamada et al.

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