Method of reclaiming a well completion brine solutions using...

Liquid purification or separation – Processes – Ion exchange or selective sorption

Reexamination Certificate

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C166S244100, C166S267000, C175S066000, C210S722000, C210S729000, C210S912000

Reexamination Certificate

active

11145281

ABSTRACT:
A method of reclaiming a well completion brine solution by using an organic chelant that is capable of discriminating between (i) iron and/or non-zinc heavy metals; and (ii) calcium and zinc. The chelant is of the formula:and may be either a neutral compound, a corresponding salt, or a corresponding quaternary salt, wherein:D is F—A (Y3)u(Y4)v;R is independently selected from Cpor CpC(O);Cpis a C1–C36hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2groups;each A is independently selected from —N and —P;Y1is independently selected from J, —[(F)—A(J)]wY6and R;J, R1, Y2, Y3, Y4, Y5and Y6are independently selected from the group consisting of —H, R, —(F)nCO2Z and —(CH2)nPO(OZ)2;each F is independently selected from a C1–C12hydrocarbyl group, optionally substituted with one or more substituents selected the group consisting of halogen, hydroxyl, sulfate, CH2CO2Z or —(CH2)nPO(OZ)2groups;Z is —H or a balanced counterion of an alkali or alkaline earth metal or NH4+;m is 0 to 7;n is 1 to 7;r+s+t is 1 or 2;u+v is 1 or 2; andw is 0 to 7provided when m is 0, no more than one of R1, Y1, Y2and Y5can be —H.

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