Method of purifying uranium tetrafluoride hydrate and preparing

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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423 16, 423253, 423260, C01G 4301

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active

042580129

ABSTRACT:
A method of preparing uranium (VI) peroxide hydrate from uranium tetrafluoride hydrate, comprising the steps of digesting uranium tetrafluoride hydrate in an aqueous acid in the presence of a fluoride complexing agent to produce an aqueous uranium solution, adjusting the aqueous uranium solution to a pH between about 1 to about 3, filtering the aqueous uranium solution to remove undissolved material, reacting the aqueous uranium solution with peroxide to precipitate uranium (VI) peroxide hydrate, and separating the precipitated uranium (VI) peroxide hydrate.

REFERENCES:
patent: 2733127 (1956-01-01), Spiegler
patent: 2770521 (1956-11-01), Spiegler
patent: 2847277 (1958-08-01), King et al.
patent: 3037840 (1962-06-01), Gregory, Jr. et al.
Bruce, F., et al., Eds., Progress in Nuclear Chemistry, Series III, Process Chemistry, Pergammon Press, N.Y. 1956, p. 20. _
Grainger, L. Uranium and Thorium, George Newnes Limited, London, 1958, pp. 31-32. _
Katz, J. et al., The Chemistry of Uranium, Part I, McGraw-Hill Book Company, Inc., New York, 1951, p. 375. _

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