Method of purifying flue gases from sulphur dioxide

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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423242, B01J 800, C01B 1700

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active

044541023

ABSTRACT:
Purification of gases from acid gas components according to the dry method means that the gas is contacted with an absorbent in a solid phase, which yields a relatively low reaction rate. In order to increase the reaction rate according to the invention, the gas is contacted with a mixture consisting partially of a solid absorbent phase and partially a liquid phase on the surface of the solid phase. At the purification of flue gases from sulphur dioxide hot gas is contacted with an absorption liquid in a drying apparatus, where evaporation of the water supplied and a reaction between sulphur dioxide and the absorption substance take place simultaneously, whereafter the solid product phase is separated from the gas in a dust separator and a slower, secondary absorption reaction is operative. In order to achieve a higher reaction rate in the dust separator, a substance is added to the flue gas which, together with other chemical species derived from the gas or the solid absorbent forms a liquid phase distributed over the surface of the solid phases. The liquid phase usually contains water and has a good solubility for reactants and reaction products.

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patent: 3966878 (1976-06-01), Pausch et al.
patent: 3976747 (1976-08-01), Shale et al.
patent: 4177158 (1979-12-01), Blue
patent: 4201751 (1980-05-01), Holter et al.
patent: 4279873 (1981-07-01), Felsvang et al.

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