Radiation imagery chemistry: process – composition – or product th – Post imaging processing – Using web or gel
Reexamination Certificate
2000-06-13
2001-10-02
Le, Hoa Van (Department: 1752)
Radiation imagery chemistry: process, composition, or product th
Post imaging processing
Using web or gel
Reexamination Certificate
active
06296993
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to a method of providing a digitized photographic image using a photochemical delivery article comprising a hydrogel containing photographic processing chemicals for photoprocessing and digitizing the resulting image. This invention can be used to provide a digitized color or black-and-white photographic image.
BACKGROUND OF THE INVENTION
The basic image-forming process of photography comprises the exposure of a silver halide photographic recording material, such as a color film, to electromagnetic radiation, and the chemical processing of the exposed material to provide a useful image. Chemical processing involves one fundamental step and one or more ancillary steps. The fundamental step is treatment of the exposed silver halide material with a developing agent wherein some or all silver ion is reduced to metallic silver, and in the case of color materials, a dye image is formed (because of a color developing agent).
For color materials, the ancillary steps include the removal of silver metal and silver salts by one or more steps of bleaching and fixing so that only a dye image remains in the processed material. These steps are commonly used to enable optical printing and to make scanning easier. During bleaching, the developed silver is oxidized to a silver salt by a suitable bleaching agent. The oxidized silver is then dissolved and removed from the material using a “fixing” agent or silver solvent in a fixing step. Black-and-white materials are desilvered using only the fixing step.
Additional photoprocessing steps may be needed including rinsing or dye stabilization that requires even more photoprocessing chemicals. In the case of color reversal materials, additional photoprocessing steps include black-and-white development, a reversal step, pre-bleaching or conditioning step and one or more rinsing steps.
All of these photoprocessing steps require preparation of the photoprocessing compositions (whether in aqueous or solid form), large or small photoprocessing tanks or reservoirs to hold the compositions, and disposal or regeneration of the “spent” compositions once a predetermined amount of exposed material has been processed. All of these operations require considerable manufacturing effort, shipping and handling of chemicals and aqueous solutions, replenishment of the solutions, and disposal of solutions into the environment. These characteristics of conventional photoprocessing are labor intensive, tedious, costly and potentially harmfull to the environment (although much work has been accomplished in the industry to make the compositions more environmentally “friendly”).
New business opportunities are thought to exist if ways can be found to minimize or obviate the problems described above. Providing photographic images (often known as “photofinishing”) is a growing business and yet there is a need to provide those images in ways that do not require some or all of the traditional photoprocessing solutions, equipment and replenishment systems.
Various research efforts have been carried out in the industry to provide new methods of imaging. For example, research has been carried out directed at putting photoprocessing chemicals directly into the imageable materials. Coated donor/receivers systems on flexible supports have been developed in recent decades for output media (such as color prints). The conventional “instant” photographic materials are examples of imaging materials that include coated and/or delivered photoprocessing chemicals. See for example, U.S. Pat. No. 4,605,608 (Bullitt).
U.S. Pat. No. 5,453,804 (Norris et al) describes a hydrogel, rolled flexible carried material that comprises an aqueous, alkaline processing composition that is used in an image transfer processing method. This material does not include a backing sheet or non-porous supporting substrate.
All of the ongoing research efforts still have some unattractive features pertaining to the delivery of the photoprocessing chemicals (identified as “photochemicals” hereinafter). To date, the need for enabling technology remains unsatisfied.
Recent digital technologies in the photographic industry offer advantages in that they can enable the user to manipulate the images after photochemical processing by scanning to create a digital representation of the image. One of these advantages is the ability to readjust the exposure by automatic tone scaling to correct for either over- or underexposure. Other uses of digitization are to crop, enlarge or otherwise modify the image, or to send the image to other users electronically for various purposes. The growing awareness of digitization of photographic images provides almost limitless possibilities for image manipulation for various purposes in a number of industries.
Thus, there is a need for simplified photoprocessing methods that include the possibility of digitization of the resulting images.
SUMMARY OF THE INVENTION
The problems noted above can be overcome with a method of providing an image in an imagewise exposed photographic silver halide material comprising at least one silver halide emulsion layer, the method comprising:
A) contacting a photochemical delivery article with a silver halide emulsion layer of the imagewise exposed photographic silver halide material to bring them into reactive association to form a laminate for a sufficient time to cause to a photochemical reaction and to provide a photographic image, the photochemical delivery article consisting essentially of a nonporous substrate having disposed thereon a hydrogel containing one or more diffusible photochemicals, and
B) scanning the photographic image formed in step A to form density representative electronic signals.
This method can be further extended by digitally manipulating the density representative electronic signals formed in B noted above to provide a digital record.
The present invention avoids the need for high precision fluid spreading required for extrusion hopper metering. It also avoids the traditional processing baths and equipment used in conventional photoprocessing and all the problems they entail.
These advantages are provided with a photochemical delivery article that can be laminated to imagewise exposed photographic silver halide materials to deliver photochemicals for image formation. This lamination operation allows photochemicals to move into and out of the imagewise exposed photographic materials for a period of time sufficient for the desired photochemical reaction(s) to occur. Once the method is finished, the contacted material needs little or no further handling. In one embodiment, drying is unnecessary before the processed material is scanned to provide density representative electronic signals in the digitization of the image.
The photochemical delivery article is a permeable matrix composed of a hydrogel that has been impregnated or swollen with one or more photochemicals prior to use. The article can be used to deliver the photochemicals in a controlled fashion to the same or different materials without additional fluid extrusion, pumping or dipping the materials into processing baths. Different delivery articles can be used in sequence to deliver the different photochemicals necessary for the various sequential photochemical reactions required for providing a color or black-and-white image. For example, in providing color negative images, one delivery article could be used to deliver a color developing agent and one or more other delivery articles could be used thereafter to desilver the material. Following all desired processing steps, the processing material can be used to provide digitized images (or a digital record) for storing, transmitting, printing, displaying or other manipulation.
The hydrogel containing delivery articles useful in this invention are advantageous because they readily absorb solvents (containing needed photochemicals), undergo rapid swelling without discemable dissolution and maintain three-dimensional networks capable of reversible deformation while maintaining their phy
Sowinski Allan F.
Szajewski Richard P.
Wildman Nigel R.
Eastman Kodak Company
Le Hoa Van
Tucker J. Lanny
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