Method of producing unsaturated aldehyde and/or unsaturated...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C562S547000

Reexamination Certificate

active

11021442

ABSTRACT:
Disclosed is a method for producing unsaturated aldehydes or unsaturated fatty acids from at least one compound selected from the group consisting of propylene, propane, (meth)acrolein, isobutylene, t-butyl alcohol, methyl-t-butyl ether and o-xylene by means of fixed-bed catalytic partial oxidation in a shell-and-tube reactor, characterized in that the reactor includes a reaction zone for producing unsaturated aldehydes as a main product, the reaction zone having an inactive material layer inserted into a position where a hot spot is to be generated in a reaction tube. A fixed-bed shell-and-tube reactor for use in the above method is also disclosed. According to the present invention, at least one layer of inactive material is packed at the point of a hot spot to control the hot spot temperature efficiently, thereby increasing the lifetime of a catalyst and producing unsaturated aldehydes and unsaturated fatty acids with high yield.

REFERENCES:
patent: 4256783 (1981-03-01), Takada et al.
patent: 5198581 (1993-03-01), Kawajiri et al.
patent: 53-030688 (1978-03-01), None
patent: 07-010802 (1995-01-01), None
patent: 11-080052 (1999-03-01), None
patent: 2001-129384 (2001-05-01), None
patent: 2001-137689 (2001-05-01), None
patent: 2001-139499 (2001-05-01), None
patent: 1020010080871 (2001-08-01), None
PCT International Search Report for Application No. PCT/KR2004/003433; International filing date: Dec. 24, 2004; Date of Mailing : Mar. 21, 2005.

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