Method of producing polyhydric compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 2900

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039681750

ABSTRACT:
A polyhydric compound is produced by catalytically disproportionating a precursor which is a lower carboxylate ester of said compound containing at least one lower carboxylate group and at least one free hydroxyl group. Most preferably the invention relates to the production of a diol by the catalytic disproportionation of a lower carboxylate diester of the diol.

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patent: 3668239 (1972-06-01), Kollar
Horsley et al., 'Azeotropic Data," (1952) pp. 64 to 68.
Lange, "Handbook of Chemistry," 10th ed. (1961), pp. 564, 565.

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