Compositions: coating or plastic – Coating or plastic compositions – Metal-depositing composition or substrate-sensitizing...
Patent
1974-10-21
1977-04-26
White, Robert F.
Compositions: coating or plastic
Coating or plastic compositions
Metal-depositing composition or substrate-sensitizing...
264 1, 264 61, 264 65, 264332, C04B 3546
Patent
active
040199150
ABSTRACT:
There is provided a method of producing a ceramic represented by the general formula of ABO.sub.3, wherein A includes Pb and at least one element selected from the group consisting of Ba and Sr and B is either of Zr or both of Zr and Ti, by hot-pressing a complex oxide obtained by calcining the mixture of the oxides of A and B characterized by that a solid solution of the oxides of Ba and/or Sr and the oxide of the element constituting B, such as BaTiO.sub.3, SrZrO.sub.3 or (Ba, Sr)ZrO.sub.3, is used as the starting oxides of Ba and/or Sr, and that the starting material contains PbO in an amount of 3 - 20 mol% in excess of that calculated for the objective composition of the final product. Ceramics produced by the method of the present invention have ferroelectric properties and are optically transparent.
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O'Bryan et al., "Enhanced Ordering of Ferroelectric Domains in PLZT Ceramics," Cer. Bull. 51[5] (1972) pp. 479-485.
Haertling et al., "Hot-Pressed (Pb,La) (Zr,Ti)O.sub.3 Ferroelectric Ceramics for Electrooptic Applications," J. Am. Cer. Soc., 54[1] (1971) pp. 1-11.
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Buckner et al, "Effects of Calcining on Sintering of Lead Zirconate-Titanate Ceramics," Cer. Bull., 51[3] (1972), pp. 218-222.
Haertling, "Hot Pressed Ferroelectric Lead Zirconate-Titanate Ceramics for Electro-Optical Applications," Cer. Bull., vol. 49, No. 6 (1970) pp. 564-568.
Matsuyama Iwao
Miyauchi Katsuki
Toda Gyozo
Hitachi , Ltd.
Parrish John
White Robert F.
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