Method of producing light absorptive surface on aluminum zinc al

Metal treatment – Compositions – Heat treating

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148 627, 148 315, 428653, 428659, C23F 502

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active

044798326

ABSTRACT:
This invention is directed to a method for producing a corrosion-resistant, composite product, such as sheet and strip, having a thin, uniformly black, light-absorptive surface layer thereon, and to the product of such method. The method includes the steps of treating a product having a coating containing both zinc and aluminum, such as galvanized strip, or up to 70% by weight, aluminum, balance essentially zinc coated strip, with an aqueous alkaline solution for a sufficient time to form a zinc-rich surface on said product, which surface is reactive with a blackening bath containing Ni and Sb, and subjecting such treated product to such blackening bath to form said thin, uniform, light-absorptive surface layer on said product. The light-absorptive surface layer has a thickness of at least 80 nm, preferably between about 100-400 nm, and an absorptance greater than about 95% over the solar radiation spectrum.

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Gogna, P. K., et al., "Selective Black Nickel Coatings on Zinc Surfaces by Chemical Conversion", Solar Energy, vol. 23, pp. 405-407 (1979).
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