Method of producing highly unsaturated compounds by reacting 1,3

Details Method of producing highly unsaturated compounds by reacting 1,3 Method of producing highly unsaturated compounds by reacting 1,3

1975-03-18

1976-09-21

Garner, Vivian

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260476R, 260491, 260497A, 260612D, 260614AA, 260642R, C07C 6728

Patent

active

039819078

ABSTRACT:
A 1,3-conjugated diene compound and a derivative of a butadiene dimer are subjected to an addition reaction over a rhodium compound. The 1,3-conjugated diene compound adds to the derivative in a molar ratio of 1:1. The derivative may be an ester, ether or alcohol. Said derivative is obtained either by reacting a carboxylic acid, an alcohol or a phenol with a butadiene over a palladium catalyst or by hydrolyzing the reaction product.

REFERENCES:
patent: 2533938 (1950-12-01), Jenner
patent: 3407224 (1968-10-01), Smutny
patent: 3534088 (1970-10-01), Bryant et al.
patent: 3562314 (1971-02-01), Shryne
March, Adv. Org. Chem.: Reactors, Mechn. & Structure, 1968, p. 603.
Alderson et al., J.A.C.S., 87, 1965, pp. 5638-5645.
Krauch et al., Name Reactions in Org. Chem., 1964, pp. 128-129.

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